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Water vapor line profile at 183-GHz: Temperature dependence of broadening, shifting, and speed-dependent shape parameters
Journal of Quantitative Spectroscopy and Radiative Transfer ( IF 2.3 ) Pub Date : 2020-12-11 , DOI: 10.1016/j.jqsrt.2020.107472
M.A. Koshelev , I.N. Vilkov , D.S. Makarov , M.Yu. Tretyakov , B. Vispoel , R.R. Gamache , D. Cimini , F. Romano , P.W. Rosenkranz

The water vapor line at 183 GHz was studied over the temperature range of 219–358 K using a spectrometer with radioacoustic detection of absorption, providing a signal-to-noise ratio of up to 8000. The study includes the first measurement of speed-dependent collisional broadening and shifting of this line for both self- and air-broadening, and their temperature dependences. The sign of self-shifting changes at about 280 K. Line-shape parameters are obtained for Voigt and quadratic speed-dependent Voigt shape factors. Temperature dependences of the line parameters are analyzed using empirical models from the literature. Theoretical Modified Complex Robert–Bonamy calculations of the line shape parameters, their temperature and speed-dependence are made over the temperature range of 200–3000 K. The measurements and calculations show very good agreement, although with some discrepancies for line shift parameters. The impact of the newly-measured line parameters on atmospheric water-vapor estimation from ground-based and satellite instruments is evaluated by simulation of downwelling and upwelling brightness temperatures and retrieved water-vapor mixing ratio, for atmospheric conditions typical of six climate zones. For the case of ground-based or limb-scanning radiometry with a background of cold space, the impact of speed-dependence is comparable to or exceeds that of measurement error and will introduce systematic errors if neglected. Therefore, consideration of speed-dependence is necessary for accurate estimation of water vapor with this line. The impact on upwelling brightness temperature is smaller.



中文翻译:

183-GHz处的水蒸气线轮廓:展宽,移动和速度相关形状参数的温度相关性

使用带辐射声吸收的光谱仪,在219–358 K的温度范围内研究了183 GHz的水蒸气线,信噪比高达8000。该研究包括首次测量速度相关性这条线的碰撞加宽和偏移是为了自膨胀和空气膨胀,以及它们的温度依赖性。自移的符号在280 K左右变化。获得线形参数是针对Voigt和与速度相关的二次Voigt形状因子。使用文献中的经验模型分析了线参数的温度依赖性。在200–3000 K的温度范围内,对线形参数,其温度和速度相关性进行了理论修正的复数Robert–Bonamy计算。测量和计算结果显示出很好的一致性,尽管线移位参数存在一些差异。针对六个气候区典型的大气条件,通过模拟下流和上升流的亮度温度以及检索到的水汽混合比,评估了新测量的线参数对地面和卫星仪器估算的大气水汽的影响。对于具有冷空间背景的地面或肢体扫描放射测量,速度依赖性的影响可与测量误差相当甚至超过,如果忽略,会引入系统误差。因此,考虑到速度相关性对于用该线精确估计水蒸气是必要的。对上升流亮度温度的影响较小。尽管线移位参数存在一些差异。针对六个气候区典型的大气条件,通过模拟下流和上升流的亮度温度以及检索到的水汽混合比,评估了新测量的线参数对地面和卫星仪器估算的大气水汽的影响。对于具有冷空间背景的地面或肢体扫描放射测量,速度依赖性的影响可与测量误差相当甚至超过,并且如果忽略,会引入系统误差。因此,考虑到速度相关性对于用该线精确估计水蒸气是必要的。对上升流亮度温度的影响较小。尽管线移位参数存在一些差异。针对六个气候区典型的大气条件,通过模拟下流和上升流的亮度温度以及检索到的水汽混合比,评估了新测量的线参数对地面和卫星仪器估算的大气水汽的影响。对于具有冷空间背景的地面或肢体扫描放射测量,速度依赖性的影响可与测量误差相当甚至超过,如果忽略,会引入系统误差。因此,考虑到速度相关性对于用该线精确估计水蒸气是必要的。对上升流亮度温度的影响较小。针对六个气候区典型的大气条件,通过模拟下流和上升流的亮度温度以及检索到的水汽混合比,评估了新测量的线参数对地面和卫星仪器估算的大气水汽的影响。对于具有冷空间背景的地面或肢体扫描放射测量,速度依赖性的影响可与测量误差相当甚至超过,并且如果忽略,会引入系统误差。因此,考虑到速度相关性对于用该线精确估计水蒸气是必要的。对上升流亮度温度的影响较小。针对六个气候区典型的大气条件,通过模拟下流和上升流的亮度温度以及检索到的水汽混合比,评估了新测量的线参数对地面和卫星仪器估算的大气水汽的影响。对于具有冷空间背景的地面或肢体扫描放射测量,速度依赖性的影响可与测量误差相当甚至超过,并且如果忽略,会引入系统误差。因此,考虑到速度相关性对于用这条线精确估计水蒸气是必要的。对上升流亮度温度的影响较小。

更新日期:2021-01-24
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