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Metal-free nucleophilic trifluoromethylselenolation via an iodide-mediated umpolung reactivity of trifluoromethylselenotoluenesulfonate
Beilstein Journal of Organic Chemistry ( IF 2.2 ) Pub Date : 2020-12-10 , DOI: 10.3762/bjoc.16.252
Kevin Grollier , Alexis Taponard , Arnaud De Zordo-Banliat , Emmanuel Magnier , Thierry Billard

We report herein a practical method to generate CF3Se (and RFSe) anions from shelf-stable reagents under iodide activation. Metal-free nucleophilic trifluoromethylselenolations have been then performed with this in situ-generated anion. Perfluoroalkylselenolations have also been described.

中文翻译:

通过碘介导的三氟甲基selenotoluenesone磺酸盐的碘伏反应,实现无金属亲核三氟甲基硒化

我们在此报告以生成CF的实用方法3- (和R ˚F- )从碘化活化下贮存稳定的试剂的阴离子。然后用该原位生成的阴离子进行了无金属亲核三氟甲基硒化反应。还描述了全氟烷基硒化。
更新日期:2020-12-10
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