当前位置:
X-MOL 学术
›
Beilstein. J. Org. Chem.
›
论文详情
Our official English website, www.x-mol.net, welcomes your
feedback! (Note: you will need to create a separate account there.)
Metal-free nucleophilic trifluoromethylselenolation via an iodide-mediated umpolung reactivity of trifluoromethylselenotoluenesulfonate
Beilstein Journal of Organic Chemistry ( IF 2.2 ) Pub Date : 2020-12-10 , DOI: 10.3762/bjoc.16.252 Kevin Grollier , Alexis Taponard , Arnaud De Zordo-Banliat , Emmanuel Magnier , Thierry Billard
Beilstein Journal of Organic Chemistry ( IF 2.2 ) Pub Date : 2020-12-10 , DOI: 10.3762/bjoc.16.252 Kevin Grollier , Alexis Taponard , Arnaud De Zordo-Banliat , Emmanuel Magnier , Thierry Billard
We report herein a practical method to generate CF3Se− (and RFSe−) anions from shelf-stable reagents under iodide activation. Metal-free nucleophilic trifluoromethylselenolations have been then performed with this in situ-generated anion. Perfluoroalkylselenolations have also been described.
中文翻译:
通过碘介导的三氟甲基selenotoluenesone磺酸盐的碘伏反应,实现无金属亲核三氟甲基硒化
我们在此报告以生成CF的实用方法3硒- (和R ˚F硒- )从碘化活化下贮存稳定的试剂的阴离子。然后用该原位生成的阴离子进行了无金属亲核三氟甲基硒化反应。还描述了全氟烷基硒化。
更新日期:2020-12-10
中文翻译:
通过碘介导的三氟甲基selenotoluenesone磺酸盐的碘伏反应,实现无金属亲核三氟甲基硒化
我们在此报告以生成CF的实用方法3硒- (和R ˚F硒- )从碘化活化下贮存稳定的试剂的阴离子。然后用该原位生成的阴离子进行了无金属亲核三氟甲基硒化反应。还描述了全氟烷基硒化。