Front Cover: Controlling Complexation Behavior of Early Lanthanides via the Subtle Interplay of their Lewis Acidity with the Chemical Stability of 5,5'‐(Azobis)tetrazolide (Z. Anorg. Allg. Chem. 23‐24/2020),Zeitschrift für anorganische und allgemeine Chemie

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Front Cover: Controlling Complexation Behavior of Early Lanthanides via the Subtle Interplay of their Lewis Acidity with the Chemical Stability of 5,5'‐(Azobis)tetrazolide (Z. Anorg. Allg. Chem. 23‐24/2020)
Zeitschrift für anorganische und allgemeine Chemie ( IF 1.1 ) Pub Date : 2020-12-09 , DOI: 10.1002/zaac.202070231
Peter Weinberger ₁ , Gerald Giester ₂ , Georg Steinhauser ₃

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The cover picture shows the molecular structure of a new type of binuclear early rare earth element complex that involves a bridging carbonato ligand, as well as 5,5'‐(azobis)tetrazolide (ZT) and aquo ligands. The compound is like a satellite sailing at the border between the Lewis acidic cation and the acid‐sensitive carbonate, with the ZTs as its solar panels. It illustrates the delicate synthesis in a subtle interplay between Lewis acidity of the Ce^IV precursor and the chemical stabilities of carbonate and ZT. More details can be found in the Article by Peter Weinberger, Gerald Giester, and Georg Steinhauser on page 1882 ff.

中文翻译：

封面：通过其路易斯酸与5,5'-（Azobis）tetrazolide的化学稳定性的微妙相互作用控制早期镧系元素的络合行为（Z. Anorg。Allg。Chem。23-24 / 2020）

封面图片显示了一种新型的双核早期稀土元素复合物的分子结构，该复合物涉及桥接的碳酸盐配体，5,5'-（偶氮双）四唑化物（ZT）和水配体。该化合物就像是在路易斯酸性阳离子和酸敏感碳酸盐之间的边界上航行的卫星，而ZTs是其太阳能电池板。它说明了Ce ^IV前体的路易斯酸度与碳酸盐和ZT的化学稳定性之间存在微妙的相互作用，从而实现了精细的合成。可以在1882页及其后的Peter Weinberger，Gerald Giester和Georg Steinhauser的文章中找到更多详细信息。

更新日期：2020-12-10

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