Front Cover Picture: Copper‐Catalyzed Synthesis of α‐Trifluoromethylacrylates from Trifluoroborylacrylates via Stereoretentive Radical Trifluoromethylation (Adv. Synth. Catal. 2/2021),Advanced Synthesis & Catalysis

当前位置： X-MOL 学术 › Adv. Synth. Catal. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Front Cover Picture: Copper‐Catalyzed Synthesis of α‐Trifluoromethylacrylates from Trifluoroborylacrylates via Stereoretentive Radical Trifluoromethylation (Adv. Synth. Catal. 2/2021)
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2020-12-10 , DOI: 10.1002/adsc.202001420
Swetha Jos ₁ , Webster L. Santos ₁

Affiliation

The front cover picture illustrates the transformation of α‐trifluoroborylacrylates to α‐trifluoromethylacrylates using inexpensive reagents such as NaSO₂CF₃ and TBHP at room temperature. The copper‐catalyzed reaction generates trifluoromethyl radical that is installed in a stereoretentive fashion. Details can be found in the communication by Swetha Jos and Webster L. Santos. Cover art credit: Carter J. Gottschalk (S. Jos, W. L. Santos, Adv. Synth. Catal. 2021, 363, 425–430; DOI: 10.1002/adsc.202000937).

中文翻译：

封面图片：通过立体定向自由基三氟甲基化反应从三氟硼基丙烯酸酯铜催化合成α-三氟甲基丙烯酸酯（高级合成，目录号2/2021）

封面图片说明了在室温下使用便宜的试剂（例如NaSO ₂ CF ₃和TBHP）将α-三氟硼丙烯酸酯转变为α-三氟甲基丙烯酸酯的过程。铜催化的反应生成三氟甲基自由基，该自由基以立体保持方式安装。可以在Swetha Jos和Webster L. Santos的来文中找到详细信息。封面信用：卡特J.夏克（S.何，WL桑托斯，进阶合成器CATAL。 。2021，363，425-430; DOI：10.1002 / adsc.202000937）。

更新日期：2021-01-19

点击分享查看原文

点击收藏

公开下载

阅读更多本刊最新论文本刊介绍/投稿指南11