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The synthesis of atalantrenes B, C and D, styrene-dimers from the seeds of Atalantia monophylla
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2020-12-10 , DOI: 10.1016/j.tetlet.2020.152716 Alexander J. Nielsen , Zirou Deng , James McNulty
中文翻译:
从单叶Atalantia种子合成Atalantrenes B,C和D苯乙烯二聚体
更新日期:2021-01-07
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2020-12-10 , DOI: 10.1016/j.tetlet.2020.152716 Alexander J. Nielsen , Zirou Deng , James McNulty
Concise syntheses of three recently reported natural products from Atalantia monophylla are reported. The syntheses required the preparation and careful dimerization of highly electron rich styrenes under acidic conditions. The present work adds to a growing body of evidence that demonstrates that synthetic utility of chiral phosphoric acids in asymmetric reactions using styrene-type compounds.
中文翻译:
从单叶Atalantia种子合成Atalantrenes B,C和D苯乙烯二聚体
简明合成了三种最近报道的来自Atalantia monophylla的天然产物。合成需要在酸性条件下制备高度富电子的苯乙烯并进行仔细的二聚。本工作增加了越来越多的证据,表明使用苯乙烯类化合物在不对称反应中合成了手性磷酸。