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Boosting low temperature propane oxidation on bamboo-mediated biosynthesis of LaCoO3 via the optimized chelating effect
Molecular Catalysis ( IF 3.9 ) Pub Date : 2020-12-09 , DOI: 10.1016/j.mcat.2020.111315
Daifeng Lin , Wei Li , Xiaoshan Feng , Yinye Chen , Xuanxu Tao , Yongjin Luo , Xinshu Xia , Baoquan Huang , Qingrong Qian , Qinghua Chen

A pure phase of LaCoO3 perovskite was low-temperature synthesized via a novel bamboo-mediated sol-gel route, which can meanwhile regulate Co species and oxygen vacancies of the catalyst by pretreatment of bamboo powder (BP). In the absence of BP, segregated phases of La2O3 and Co3O4 were found. Characterization results reveal that COO- in BP performs as a complexing agent to chelate metal ions, while the −OH groups can promote the dispersion of precursors in the formed sol solution. On the other hand, chelation effect together with bio-reduction of organic carbon is in charge of large content of bulk Co2+ in LaCoO3, resulting in high amounts of oxygen vacancies that are helpful for total propane oxidation. However, Na+ and K+ species originated from BP easily lead to the formation of carbonate species on the catalyst surface, playing a negative role in propane oxidation activity. Thus, an optimum pretreatment under acid solution (pH = 1) is adopted to address the above issue. As a result, BP-1-mediated (BP pretreated under pH = 1 solution) biosynthesis of LaCoO3 exhibits a significantly high reaction rate of 3.78 μmolC3H8 g−1·s−1 at 300 °C. Moreover, the obtained catalyst delivers excellent thermal stability against 5 vol% H2O and 5 vol% CO2.



中文翻译:

通过优化的螯合效应促进低温丙烷氧化对竹介导的LaCoO 3生物合成的影响

通过新型的竹介导的溶胶-凝胶法低温合成了LaCoO 3钙钛矿的纯相,同时可以通过预处理竹粉(BP)调节催化剂的Co种类和氧空位。在没有BP的情况下,发现了La 2 O 3和Co 3 O 4的偏析相。表征结果表明,BP中的COO-作为螯合金属离子的络合剂,而-OH基团可以促进前体在形成的溶胶溶液中的分散。另一方面,螯合效应与有机碳的生物还原一起导致LaCoO 3中大量的大量Co 2+含量。,导致大量的氧空位,有助于丙烷的完全氧化。但是,源自BP的Na +和K +物种很容易导致在催化剂表面形成碳酸盐物种,对丙烷氧化活性起负面作用。因此,采用了在酸性溶液(pH = 1)下的最佳预处理可以解决上述问题。其结果是,BP-1介导的(BP在pH预处理= 1种溶液)LaCoO的生物合成3个展品3.78微摩尔一个显著高的反应速率C3H8 克-1 ·秒-1在300℃下。此外,所获得的催化剂对5体积%的H 2 O和5体积%的CO 2具有优异的热稳定性。

更新日期:2020-12-10
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