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Biomass-derived activated carbon electrode coupled with a redox additive electrolyte for electrical double-layer capacitors
Journal of Nanoparticle Research ( IF 2.1 ) Pub Date : 2020-12-09 , DOI: 10.1007/s11051-020-05104-1
Nghia Trong Nguyen , P.A. Le , Viet Bac T. Phung

Electrical double-layer capacitors (EDLCs) using a biomass-derived activated carbon electrode with Na2SO4–NaI–KI as a redox additive electrolyte were investigated. Biomass-derived activated carbon materials from pomelo peels were prepared by chemical activation in potassium hydroxide followed by carbonization. The biomass-derived activated carbon has a high specific surface area of 1360 m2 g−1, which is suitable for electrode materials. Moreover, a stable couple inorganic redox additive electrolyte were studied by the addition of NaI and KI to Na2SO4 forming a redox additive electrolyte. The electrical double-layer based on activated carbon/Na2SO4–NaI–KI/activated carbon has an excellent specific capacitance (334.3 F g−1), which is 412% higher in comparison with that of activated carbon/Na2SO4/activated carbon (81.14 F g−1) at the same current density of 0.5 A g−1. The EDLC using Na2SO4–NaI–KI electrolyte has a high energy density of 22.75 W h kg−1, which is approximately four times higher than EDLCs based on Na2SO4 (5.52 W h kg−1).



中文翻译:

生物质衍生的活性炭电极与氧化还原添加剂电解质结合,用于双电层电容器

研究了使用生物质衍生的活性炭电极,Na 2 SO 4 -NaI-KI作为氧化还原添加剂电解质的双电层电容器(EDLC)。通过在氢氧化钾中化学活化,然后碳化,来制备柚皮中生物质衍生的活性炭材料。来自生物质的活性炭具有1360m 2  g -1的高比表面积,其适合于电极材料。此外,通过向Na 2 SO 4中添加NaI和KI以形成氧化还原添加剂电解质,研究了稳定的偶合无机氧化还原添加剂电解质。基于活性炭/ Na 2 SO的双电层4 –NaI–KI /活性炭具有优异的比电容(334.3 F g -1),比活性炭/ Na 2 SO 4 /活性炭(81.14 F g -1)高出412%。 0.5 A g -1的相同电流密度。使用Na 2 SO 4 -NaI-KI电解质的EDLC具有22.75 W h kg -1的高能量密度,大约是基于Na 2 SO 4的EDLC (5.52 W h kg -1)的四倍。

更新日期:2020-12-09
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