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Effect of Dy substitution in the giant magnetocaloric properties of HoB2
Science and Technology of Advanced Materials ( IF 7.4 ) Pub Date : 2020-12-07
Pedro Baptista de Castro, Kensei Terashima, Takafumi D. Yamamoto, Suguru Iwasaki, Ryo Matsumoto, Shintaro Adachi, Yoshito Saito, Hiroyuki Takeya, Yoshihiko Takano

Recently, a massive magnetocaloric effect near the liquefaction temperature of hydrogen has been reported in the ferromagnetic material HoB2. Here we investigate the effects of Dy substitution in the magnetocaloric properties of Ho1-x Dy x B2 alloys (x = 0, 0.3, 0.5, 0.7, 1.0). We find that the Curie temperature (T C) gradually increases upon Dy substitution, while the magnitude of the magnetic entropy change |ΔS M| and adiabatic temperature change ΔT ad showed a gradual decrease. On the other hand, due to the presence of successive transitions in these alloys, the peak height of the above magnetocaloric properties tends to be kept in a wide temperature range, leading to a relatively robust figure of merit in a wide temperature span. These alloys could be interesting candidates for magnetic refrigeration in the temperature range of 10 – 60 K.



中文翻译:

Dy取代对HoB2的巨大磁热性质的影响

近来,在铁磁材料HoB 2中已经报道了在氢的液化温度附近的大量磁热效应。在这里,我们研究了Dy置换对Ho 1- x Dy x B 2合金(x = 0、0.3、0.5、0.7、1.0)的磁热性质的影响。我们发现居里温度(T C)在Dy取代后逐渐增加,而磁熵变的幅度| ΔS M | 和绝热温度变化ΔT ad 显示逐渐减少。另一方面,由于这些合金中存在连续的转变,上述磁热性质的峰高趋于保持在宽的温度范围内,从而导致在宽的温度范围内相对稳健的品质因数。这些合金可能是10 – 60 K温度范围内磁制冷的有趣候选材料。

更新日期:2020-12-07
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