Recent Advances and Uses of (Me4N)XCF3 (X=S, Se) in the Synthesis of Trifluoromethylthiolated and Trifluoromethylselenolated Compounds,Asian Journal of Organic Chemistry

当前位置： X-MOL 学术 › Asian J. Org. Chem. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Recent Advances and Uses of (Me4N)XCF3 (X=S, Se) in the Synthesis of Trifluoromethylthiolated and Trifluoromethylselenolated Compounds
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-12-04 , DOI: 10.1002/ajoc.202000575
Xi‐Hui Yang ₁ , Denghu Chang ₁ , Rong Zhao ₁ , Lei Shi _{1,

2}

Affiliation

The introduction of trifluoromethylthio (SCF₃) and trifluoromethylseleno (SeCF₃) substituents into organic molecules significantly improves the electron‐withdrawing and lipophilic properties of their parent compounds. Therefore, a vast class of versatile reagents were employed to access the corresponding fluorine‐containing compounds. Among them, tetramethylammonium salts, such as (Me₄N)SCF₃ and (Me₄N)SeCF₃, have been employed as practical and efficient non‐metal reagents for developing efficient trifluoromethylthiolation and trifluoromethylselenolation in recent years. This Minireview systematically illustrates the application of (Me₄N)XCF₃ (X=S, Se) in the synthesis of trifluoromethylthiolated and trifluoromethylselenolated compounds, and its content is divided into two categories: transition‐metal‐catalyzed reactions, and transition‐metal‐free reactions.

中文翻译：

（Me4N）XCF3（X = S，Se）在三氟甲基硫代和三氟甲基硒代化合物的合成中的最新进展和应用

在有机分子中引入三氟甲硫基（SCF ₃）和三氟甲基硒基（SeCF ₃）取代基可显着改善其母体化合物的吸电子和亲脂性。因此，使用了多种通用试剂来访问相应的含氟化合物。其中，近年来，诸如（Me ₄ N）SCF ₃和（Me ₄ N）SeCF _3的四甲基铵盐已被用作实用有效的非金属试剂，用于开发有效的三氟甲基硫醇化和三氟甲基硒化作用。此Minireview系统地说明了（Me ₄ N）XCF _3的应用（X = S，Se）在三氟甲基硫醇化和三氟甲基硒化的化合物的合成中，其含量分为两类：过渡金属催化反应和无过渡金属反应。

更新日期：2021-01-18

点击分享查看原文

点击收藏

阅读更多本刊最新论文本刊介绍/投稿指南11