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Immobilization and mitigation of chromium toxicity in aqueous solutions and tannery waste-contaminated soil using biochar and polymer-modified biochar
Chemosphere ( IF 8.1 ) Pub Date : 2020-12-04 , DOI: 10.1016/j.chemosphere.2020.129198
Muhammad Imran Rafique , Adel R.A. Usman , Munir Ahmad , Mohammad I. Al-Wabel

This study was conducted to investigate the potential of Jujube (Ziziphus jujube L) wood waste-derived biochar (BC) and its derivative polymer-modified biochar (PBC) in removing hexavalent chromium (CrVI) from aqueous solutions and in achieving Cr stabilization in tannery waste-contaminated soil. BC was produced at three different pyrolysis temperature (300 °C, 500 °C, 700 °C) and was polymerized with acrylamide and N, N1 methylenebisacrylamide. The results showed that CrVI adsorption is a function of the pH and CrVI initial concentration of the solution. The PBC showed highest sorption efficiency for CrVI removal, which amounted to 76.4%–99.6% of the CrVI overall initial concentrations (5–40 mg L−1) at an initial pH of 2. In greenhouse, wheat (Triticum aestivum L) was cultivated as a test crop in pots with tannery waste-contaminated soil along with BCs and PBCs amendments. The BC and PBC amended soil showed 47.7% and 65% less Cr uptake by the plant roots in comparison with unamended soil, respectively. In addition, zero concentration of Cr in the plant shoots was noted with the PBC-amended soil, while the Cr concentration in the shoots was decreased by 89% with the BC-amended soil. Thus, it was concluded that BC and PBC have great potential in removing CrVI from aqueous phases and in decreasing the Cr mobility and bioavailability in soil.



中文翻译:

使用生物炭和聚合物改性的生物炭固定化并减轻水溶液和制革厂废物污染土壤中铬的毒性

这项研究的目的是研究枣木废料生物炭(BC)及其衍生的聚合物改性生物炭(PBC)在去除水溶液中的六价铬(Cr VI)和实现铬稳定方面的潜力。制革厂废物污染的土壤。BC在三种不同的热解温度(300°C,500°C,700°C)下生产,并与丙烯酰胺和N,N1亚甲基双丙烯酰胺聚合。结果表明,Cr VI吸附是溶液的pH和Cr VI初始浓度的函数。PBC去除Cr VI的吸附效率最高,占Cr VI的76.4%–99.6%。初始pH值为2时,总初始浓度为(5-40 mg L -1)。在温室中,将小麦(Triticum aestivum L)种植在装有制革废料污染土壤以及BCs和PBCs改良剂的盆中作为试验作物。BC和PBC改良土壤与未改良土壤相比,植物根系吸收的Cr分别少47.7%和65%。此外,在PBC改良土壤中,植物芽中的Cr浓度为零,而在BC改良土壤中,芽中的Cr浓度降低了89%。因此,可以得出结论,BC和PBC在去除水相中的Cr VI以及降低土壤中Cr的迁移率和生物利用度方面具有巨大潜力。

更新日期:2020-12-10
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