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Leachate after aerobic stabilization of municipal solid waste supplemented by waste glycerine from saponification to improve biogas production during co-digestion
Biomass & Bioenergy ( IF 5.8 ) Pub Date : 2020-12-02 , DOI: 10.1016/j.biombioe.2020.105908
Katarzyna Bernat , Magdalena Zaborowska , Irena Wojnowska-Baryła , Beata Piotrowicz

Co-digestion of leachate from aerobic stabilization of OFMSW (leachateOFMSW) with waste glycerine (WG) from saponification is a promising approach for municipal waste and wastewater treatment. The effect of feedstock composition on co-digestion efficiency was examined. Two feedstocks with different contents of WG (6%, 13%) were used, which affected the COD:TKN ratios in those feedstocks (60, 100). LeachateOFMSW provided nitrogen and the micro- and macroelements. In both feedstocks, the N–NH4:TKN ratio was low (0.08), indicating that the dominant form of nitrogen was organic nitrogen (Norg). Co-digestion was carried out in upflow anaerobic-sludge blanket reactors (37 ± 2 °C; OLR, 4 kg COD m−3 d−1).

This process ensured highly effective COD removal (over 97%). At a feedstock COD:TKN ratio of 60, specific biogas production (SBP) was ca. 0.22 m3 kg−1 COD, and methane content, 61.6%. Increasing the COD:TKN ratio to 100 significantly increased SBP to ca. 0.36 m3 kg−1 COD, but reduced biogas quality (54.2% CH4). Although Norg had to be ammonified to ammonium because of the low N–NH4:TKN ratio in the feedstocks, the ammonium concentration in the post-processing wastewater remained low. Moreover, the low ammonium concentrations meant that the pH (8.8) did not have a toxic effect on anaerobic co-digestion (free ammonia concentrations were merely ca. 28 and 5.5 mg L−1, respectively). However, at higher feedstock COD:TKN ratios than those tested, ammonium could be exhausted, which would impede methane production. These results indicate that WG is an effective co-substrate for leachateOFMSW if an appropriate amount of WG is added to the feedstock.



中文翻译:

对城市固体废物进行有氧稳定后的渗滤液,再加上皂化处理产生的废甘油,以提高共消化期间的沼气产量

将OFMSW的好氧稳定液中的渗滤液(渗滤液OFMSW)与皂化的废甘油(WG)共消化是一种用于市政废物和废水处理的有前途的方法。考察了原料组成对共消化效率的影响。使用了两种具有不同WG含量的原料(6%,13%),这会影响这些原料中的COD:TKN比率(60,100)。渗滤液OFMSW提供了氮以及微量元素宏观元素。在两种原料中,N–NH 4 ∶TKN的比率都较低(0.08),表明氮的主要形式是有机氮(N org)。共消化在上流厌氧污泥床反应器(37±2°C; OLR,4 kg COD m -3 d -1)。

此过程确保了高效的COD去除(超过97%)。当原料的COD:TKN比为60时,特定的沼气产量(SBP)约为10。0.22 m 3  kg -1 COD和甲烷含量为61.6%。将COD:TKN比率提高到100,可将SBP显着提高至约200。0.36 m 3  kg -1 COD,但沼气质量降低(54.2%CH 4)。尽管由于N–NH 4含量低,N org必须被氨化为铵。原料中的:TKN比,后处理废水中的铵浓度仍然很低。此外,低铵浓度意味着pH(8.8)对厌氧共消化没有毒性作用(游离氨的浓度分别仅为28和5.5 mg L -1)。但是,如果原料COD:TKN的比率高于测试的比率,则会消耗掉铵,这会阻碍甲烷的生产。这些结果表明,如果在原料中添加适量的WG,则WG是渗滤液OFMSW的有效共基质。

更新日期:2020-12-03
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