Triphilic pentablock copolymers with a perfluorinated block in center position have been synthesized by atom transfer radical polymerization (ATRP) and Cu(I) catalyzed azidealkyne cycloaddition (CuAAC). Nanoaggregates are formed with a mixed core of lipophilic and fluorophilic blocks surrounded by a corona of hydrophilic blocks. Jörg Kressler and coworkers provide more details in their article on page 3322. (DOI: 10.1002/pol.20200582)

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通过原子转移自由基聚合（ATRP）和Cu（I）催化的叠氮炔环加成反应（CuAAC）合成了中心位置带有全氟嵌段的三亲五嵌段共聚物。纳米聚集体由亲脂性和亲氟性嵌段的混合核形成，并被亲水性嵌段的电晕包围。约格·克雷斯勒（JörgKressler）及其同事在其第3322页的文章中提供了更多详细信息。（DOI：10.1002 / pol.20200582）