The phosphorus structures in CaO–SiO₂–P₂O₅ glasses were analyzed by Raman spectroscopy and integral Raman intensities of [PO₄]-tetrahedrons were calibrated by ³¹P MAS-NMR spectroscopy. Spectral results showed the presence of Q⁰(P) and Q¹(P), and calculated values of Raman scattering coefficients of Q⁰(P), Q¹(P) units were 1 and 0.576, respectively. Good agreement between experimental and theoretical values of non-bridging oxygen number per coordinated atom indicated the reliability of evaluating Raman scattering coefficients of Qⁿ(P). Quantitative Raman analysis indicated that CaO exerted stronger ability to depolymerize [PO₄]-tetrahedrons rather than [SiO₄]-tetrahedrons with increasing basicity under the condition of higher degree of polymerization. P₂O₅ added to silicate melt could cause an increase in amount of Q²(Si), Q³(Si) and Q⁴(Si) units due to stronger stability of P–O–Ca linkages than that of Si–O–Ca linkages. Moreover, P⁵⁺ ions could be partly replaced with Si⁴⁺, forming Q¹(Si+P) and Q²(Si+P) units.

通过拉曼光谱分析CaO-SiO ₂ -P ₂ O ₅玻璃中的磷结构，并通过³¹ P MAS-NMR光谱校正[PO ₄ ]-四面体的积分拉曼强度。光谱结果表明存在Q ⁰（P）和Q ¹（P），并且计算的Q ⁰（P），Q ¹（P）单位的拉曼散射系数分别为1和0.576。每个配位原子的非桥接氧数的实验值与理论值之间的一致性很好，表明评估Q ⁿ拉曼散射系数的可靠性（P）。拉曼定量分析表明，在较高聚合度的条件下，随着碱度的增加，CaO可以使[PO ₄ ]-四面体的解聚能力强于[SiO ₄ ]-四面体。由于P–O–Ca键的稳定性比Si–O更强，因此添加到硅酸盐熔体中的P ₂ O ₅可能导致Q ²（Si），Q ³（Si）和Q ⁴（Si）单元数量增加。–Ca链接。此外，P ⁵⁺离子可以部分被Si ⁴⁺取代，形成Q ¹（Si + P）和Q ²（Si + P）单元。