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CAN‐mediated Oxidative Coupling‐Reaction of Xanthenes with Enaminones
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-12-01 , DOI: 10.1002/ajoc.202000617
Changyuan Zhang 1 , Yun Qiu 1 , Jiantao Zhang 2 , Lulu Chen 1 , Shuting Xu 1 , Huosheng Guo 1 , Jian Luo 1 , Yao Tan 1
Affiliation  

An efficient CAN‐mediated C−C bond formation in the oxidative reactions of xanthenes with enaminones under mild reaction conditions are described. A variety of 9H‐xanthene‐9‐ylidene aldehydes could be synthesized in up to 90% yield via one‐pot manner with good functional group compatibility, which achieved the simultaneous construction of carbon‐carbon double bond and carbon‐oxygen double bond.

中文翻译:

黄嘌呤与烯胺酮的CAN介导的氧化偶联反应

描述了在温和的反应条件下,黄嘌呤与烯胺酮的氧化反应中有效的CAN介导的CC键形成。通过一锅法以良好的官能团相容性可以合成高达90%收率的多种9H-蒽并-9-亚蒽醛,实现了碳-碳双键和碳-氧双键的同时构建。
更新日期:2021-01-18
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