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MXene/SnO2 heterojunction based chemical gas sensors
Sensors and Actuators B: Chemical ( IF 8.0 ) Pub Date : 2020-12-01 , DOI: 10.1016/j.snb.2020.129275
Tingting He , Wei Liu , Tan Lv , Mingsheng Ma , Zhifu Liu , Alexey Vasiliev , Xiaogan Li

Two dimensional (2D) MXene decorated by the SnO2 nanoparticles has been successfully synthesized by the hydrothermal method. The formed MXene/SnO2 heterojunction based chemirestistive-type sensors exhibit an excellent sensitivity and selectivity to different concentrations of NH3 from 0.5 to 100 ppm at room temperature. The enhanced sensing properties can be attributed to two major factors. On one hand, 2D MXene provides a matrix which has a unique, selective adsorption ability to ammonia and good conductivity that makes the room-temperature sensing of the heterojunction based sensor feasible. On the other hand, the difference in the Fermi level of the 2D MXene and SnO2 drives the charge transfer at the interface of the heterojunctions enriching the electrons on the surface region of SnO2 and consequently enhancing the sensitivity. Furthermore, a wireless sensor made from an inductor-capacitor (LC) antenna and the as-synthesized MXene/SnO2 heterojunctions fabricated by the low-temperature-cofired ceramic technique (LTCC) was preliminary investigated. The wireless sensor shows a even faster response/recovery speeds (<30 s) and more stable response to different concentrations of ammonia when the response was expressed in the mode of resonant frequency indicating a promising practical application.



中文翻译:

基于MXene / SnO 2异质结的化学气体传感器

通过水热法成功地合成了由SnO 2纳米粒子修饰的二维(2D)MXene 。所形成的基于MXene / SnO 2异质结的化学弹性型传感器在室温下对0.5至100 ppm的不同NH 3浓度具有出色的灵敏度和选择性。增强的感测特性可以归因于两个主要因素。一方面,二维MXene提供了一种对氨具有独特的选择性吸附能力和良好的导电性的基质,这使得基于异质结的传感器的室温感测变得可行。另一方面,二维MXene和SnO 2的费米能级不同驱动异质结界面处的电荷转移,使SnO 2表面区域上的电子富集,从而提高了灵敏度。此外,初步研究了由电感电容器(LC)天线和通过低温共烧陶瓷技术(LTCC)制成的合成MXene / SnO 2异质结制成的无线传感器。当以共振频率模式表示响应时,无线传感器显示出更快的响应/恢复速度(<30 s)和对不同浓度氨气的更稳定响应,这表明它有希望的实际应用。

更新日期:2020-12-11
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