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A highly selective colorimetric and fluorescent probe for Cu2+ based diarylethene with a diaminomaleonitrile unit
Tetrahedron ( IF 2.1 ) Pub Date : 2020-11-30 , DOI: 10.1016/j.tet.2020.131788
Xutang Liu , Hongliang Liu , Xugang Tang , Gang Liu , Shouzhi Pu

A novel photochromic diarylethene derivative containing a diaminomaleonitrile unit (1O) was synthesized and its colorimetric and fluorescent turn-on sensing of Cu2+ in acetonitrile solution was demonstrated. Both of its open- and closed-loop isomers (1O and 1C) were highly selective for Cu2+ with obvious absorption and color transforms. Moreover, the addition of Cu2+ enhanced the fluorescence of 1O up to 174-fold with the concomitant color change from colorless to blue. The limit of detections (LODs) for Cu2+ was determined to be 1.76 × 10−8 mol L−1. The stoichiometry of 1: 1 between the probe 1O and Cu2+ was measured in Job’s plot and ESI-MS. Most remarkably, the probe 1O could be used to detect Cu2+ in test strip.



中文翻译:

具有二氨基马来腈单元的基于Cu 2+的二芳基乙烯的高选择性比色和荧光探针

含有二氨基单元(A新型光致变色二芳基乙烯衍生物1O合成)和它的比色和荧光接通铜的感测2+在乙腈溶液中证实。它的开环和闭环异构体(1O1C)对Cu 2+的选择性都很高,具有明显的吸收和颜色转换。此外,Cu 2+的添加增强了1O的荧光强度,最高可达174倍,同时颜色从无色变为蓝色。Cu 2+的检出限(LODs)确定为1.76×10 -8  mol L -1。在乔布氏图和ESI-MS中测量探针1O和Cu 2+之间的化学计量比为1:1 。最显着的是,探针1O可用于检测测试条中的Cu 2+

更新日期:2020-12-17
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