Boron Carbon Nitride Thin Films: From Disordered to Ordered Conjugated Ternary Materials,Journal of the American Chemical Society

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Boron Carbon Nitride Thin Films: From Disordered to Ordered Conjugated Ternary Materials
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2020-11-27 , DOI: 10.1021/jacs.0c10945
Paolo Giusto ₁ , Hiroki Arazoe ₂ , Daniel Cruz _{3,

4} , Paola Lova ₅ , Tobias Heil ₁ , Takuzo Aida ₂ , Markus Antonietti ₁

Affiliation

We present an innovative method for the synthesis of boron carbon nitride thin film materials in a simple furnace setup, using commonly available solid precursors and relatively low temperature compared to previous attempts. The as-prepared structural and optical properties of thin films are tuned via the precursor content, leading to a sp2-conjugated boron nitride–carbon nitride mixed material, instead of the commonly reported boron nitride–graphene phase segregation, with tunable optical properties such as band gap and fluorescence.

中文翻译：

硼碳氮化物薄膜：从无序到有序共轭三元材料

我们提出了一种在简单的炉子设置中合成硼碳氮化物薄膜材料的创新方法，与以前的尝试相比，使用常用的固体前体和相对较低的温度。所制备的薄膜的结构和光学特性通过前驱体含量进行调节，从而产生 sp2 共轭氮化硼 - 氮化碳混合材料，而不是通常报道的氮化硼 - 石墨烯相分离，具有可调光学特性，例如带隙和荧光。

更新日期：2020-11-27

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