There is a surge of interest to expand the search for entirely new classes of molecular magnets as the emergence of information storage and quantum computing devices. Prussian blue analogues as a family of molecular magnets are especially attracting wide attention due to their large number of derivatives with a range of magnetic ordering temperature from cryogenic to room temperature. This review presents Prussian blue analogues as multifunctional molecular magnets, which involves the development of molecular magnet syntheses and crystal structures, and magnetic properties under external stimuli. In addition, the porous network structures and vacancy order of Prussian blue analogues present a wide capability to interact with water molecules and gas adsorption. External stimuli, such as thermal, pressure, electric and magnetic field and photoexcitation, play an important role in controlling the hidden states and cooperative phenomena of high temperature molecular magnets based on Prussian blue analogues.

随着信息存储和量子计算设备的出现，人们对寻找全新种类的分子磁体的兴趣激增。普鲁士蓝类似物作为分子磁体家族尤其受到广泛关注，因为它们具有大量的衍生物，其磁定序温度范围从低温到室温。这篇综述提出了普鲁士蓝类似物作为多功能分子磁体，它涉及分子磁体合成和晶体结构的发展，以及在外部刺激下的磁性。此外，普鲁士蓝类似物的多孔网络结构和空位顺序具有与水分子和气体吸附相互作用的广泛能力。外部刺激，例如热，压力，