The most recent developments on Pickering emulsions deal with the design of responsive emulsions able to undergo fast destabilization under the effect of an external stimulus. In this scenario, soft colloidal particles like microgels are considered novel class suitable emulsifiers. Microgels particles self-assemblies are highly deformable at interfaces covering higher surfaces than hard particles and their interfacial behavior strongly depends on external-stimuli. Microgels are very diverse owing to the large variety of them from the point of view of possible combinations of stimuli-responsiveness and different microstructures (crosslinking density and distribution). Herein, we illustrate the use of different types of responsive microgels not only from a structural point of view but also even from physical one. For that, the effect of different microgels parameters such as internal structure and charge density on mechanical properties of the interface will be discussed.

Pickering乳液的最新发展涉及响应性乳液的设计，该乳液在外部刺激作用下能够快速失稳。在这种情况下，柔软的胶体颗粒（如微凝胶）被认为是新型适用的乳化剂。微凝胶颗粒的自组装在比硬颗粒覆盖更高表面的界面处高度变形，并且它们的界面行为强烈取决于外部刺激。从刺激响应性和不同微观结构（交联密度和分布）的可能组合的角度来看，微凝胶由于种类繁多而非常多样化。在此，我们不仅从结构的角度而且甚至从物理的角度说明了不同类型的反应性微凝胶的使用。为了那个原因，