Remote functional group directed C–H activation by an Ir(III) phenanthroline complex,Chemical Communications

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Remote functional group directed C–H activation by an Ir(III) phenanthroline complex
Chemical Communications ( IF 4.3 ) Pub Date : 2020-11-20 , DOI: 10.1039/d0cc06298g
Rozalie Sharon Genevieve Corea _{1,

2,

3,

4} , Scott Gronert _{1,

2,

3,

4,

5}

Affiliation

The regioselectivity of the C–H activation of 1-butanol and 1-methoxybutane by an iridium(III) phenanthroline complex was studied in the gas phase and revealed activation at gamma and delta carbons. In the ether, nearly exclusive gamma activation was observed. DFT calculations were used to explore the origin of this substrate-driven selectivity. The data show that the iridium(III) complex is a potent and potentially highly selective remote C–H activation agent.

中文翻译：

远程官能团通过Ir（III）菲咯啉配合物指导CH活化

在气相中研究了铱（III）菲咯啉络合物对1-丁醇和1-甲氧基丁烷的CH活化的区域选择性，并揭示了在γ和δ碳上的活化。在乙醚中，观察到几乎排他的γ活化。DFT计算用于探索这种底物驱动的选择性的起源。数据表明，铱（III）络合物是一种有效的且可能具有高度选择性的远程CH活化剂。

更新日期：2020-11-27

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