Palladium-catalysed annulative allylic alkylation for the synthesis of benzannulated heteroarenes,Chemical Communications

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Palladium-catalysed annulative allylic alkylation for the synthesis of benzannulated heteroarenes
Chemical Communications ( IF 4.3 ) Pub Date : 2020-11-20 , DOI: 10.1039/d0cc06695h
Sonu Yadav _{1,

2,

3,

4,

5} , S. S. V. Ramasastry _{1,

2,

3,

4,

5}

Affiliation

A conceptually novel intramolecular allylic alkylation strategy is developed for the synthesis of carbazoles and dibenzothiophenes. In an unusual event, palladium catalyses the formation of π-allylpalladium complexes of the respective (2-methylindol-3-yl)allyl acetates and subsequently facilitates the benzannulation process.

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