Hydrolysis of Zr(BH₄)₄·8NH₃ in deionized water can generate high purity hydrogen at room temperature. However, the sluggish hydrolysis kinetics of Zr(BH₄)₄·8NH₃ hinders its practical use. To improve its hydrogen generation properties, the effects of magnetic stirring, changing hydrolysis solution and tuning the ammonia coordination number on the hydrolysis properties of Zr(BH₄)₄·8NH₃ were investigated. Results show that both changing hydrolysis solution and tuning the ammonia coordination number can enhance the hydrolysis kinetics. The hydrolysis kinetics properties of Zr(BH₄)₄·8NH₃ were significantly improved in MgCl₂ and CoCl₂ solutions. The Zr(BH₄)₄·xNH₃ (x ≤ 8) samples were synthesized by a ball-milling method with different ammonization time (10, 60 and 180 min). Both the hydrolysis kinetics and hydrogen yield of Zr(BH₄)₄·xNH₃ (x ≤ 8) were enhanced as the ammonia coordination number (x) decreased. Thus, tuning ammonia coordination number is an effective way to control the hydrolysis properties of Zr(BH₄)₄·xNH₃ (x ≤ 8).

Zr（BH ₄）₄ ·8NH ₃在去离子水中的水解可在室温下产生高纯度的氢气。然而，Zr（BH ₄）₄ ·8NH ₃的缓慢的水解动力学阻碍了其实际应用。为了提高其产氢性能，研究了磁力搅拌，改变水解溶液和调节氨配位数对Zr（BH ₄）₄ ·8NH ₃水解性能的影响。结果表明，改变水解溶液和调节氨配位数均可提高水解动力学。Zr（BH ₄）的水解动力学性质在MgCl ₂和CoCl ₂溶液中₄ ·8NH ₃显着改善。Zr（BH ₄）₄ ·xNH ₃（x≤8 ）样品是通过球磨法在不同的氨化时间（10、60和180分钟）下合成的。Zr（BH ₄）₄ ·xNH ₃（x≤8 ）的水解动力学和氢产率均随着氨配位数（x）的降低而提高。因此，调节氨配位数是控制Zr（BH ₄）₄ ·xNH ₃（x≤8 ）水解性能的有效方法。