当前位置: X-MOL 学术J. Mater. Sci. Mater. Electron. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Colossal dielectric response in erbium iron garnet ceramics
Journal of Materials Science: Materials in Electronics ( IF 2.8 ) Pub Date : 2020-11-27 , DOI: 10.1007/s10854-020-04775-9
Jia Zheng , Qingshan Fu , Xinghan Chen , Chiranjib Chakrabarti , Pengjian Wang , Hongxia Yin , Canglong Li , Yang Qiu , Songliu Yuan

Polycrystalline Er3Fe5O12 ceramic sample was synthesized by a solid-state reaction technique. The dielectric properties of the sample were experimentally studied. A colossal dielectric constant more than 103 was observed over a wide temperature and frequency range. The dielectric relaxation in the sample was identified by the measurement of permittivity modulus, impedance spectroscopy, and conductivity in detail. At relatively low temperatures (T < 600 K), the dielectric relaxation under high frequencies (f ≥ 50 kHz) is triggered by the dipolar effect accompanied by the Fe2+ and Fe3+ charge transitions, while that under low frequencies (f ≤ 50 kHz) is mainly be associated with the Maxwell–Wagner effect. Moreover, a low-frequency dielectric relaxation at high temperatures (T ≥ 600 K) is probably evolving from the contribution of oxygen vacancies and grain boundaries, which is also suggested to be the origin of the colossal dielectric constant.



中文翻译:

iron铁石榴石陶瓷的巨大介电响应

通过固相反应技术合成了多晶的Er 3 Fe 5 O 12陶瓷样品。对样品的介电性能进行了实验研究。在较宽的温度和频率范围内观察到大于10 3的巨大介电常数。通过测量介电常数,阻抗谱和电导率来确定样品中的介电弛豫。在相对低的温度(Ť  <600 K),在高频率下的介电弛豫(˚F  ≥50千赫)由伴随Fe的偶极效应触发2+和Fe 3+电荷转移,而在低频率(˚F  ≤50千赫)主要与麦克斯韦-瓦格纳效果相关联。此外,在高温(低频介电弛豫Ť  ≥600 K)可能是从氧空位和晶界的贡献,这是还建议是巨大的介电常数的起源进化。

更新日期:2020-11-27
down
wechat
bug