Light-induced excited spin state trapping in iron(III) complexes,Inorganic Chemistry Frontiers

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Light-induced excited spin state trapping in iron(III) complexes
Inorganic Chemistry Frontiers ( IF 6.1 ) Pub Date : 2020-11-24 , DOI: 10.1039/d0qi01188f
Manabu Nakaya _{1,

2,

3,

4,

5} , Ryo Ohtani _{1,

2,

5,

6,

7} , Leonard F. Lindoy _{8,

9,

10,

11} , Shinya Hayami _{1,

5,

12,

13,

14}

Affiliation

Spin crossover in iron(II) and iron(III) complexes continues to receive much attention for the construction of molecular devices due to the presence of functionalities arising from their spin state switching behavior. Notably, some such compounds are associated with a light-induced excited spin-state trapping (LIESST) effect, which is responsible for the optical switching of their spin states. However, as opposed to iron(II) complexes, reports of iron(III) complexes that exhibit a LIESST effect are somewhat limited. This review presents an overview of the reported examples of SCO iron(III) systems that display LIESST effects.

中文翻译：

铁（III）配合物的光诱导激发自旋态陷阱

铁（II）和铁（III）配合物中的自旋交叉因其自旋状态转换行为而引起的功能性的存在，在分子装置的构造方面继续受到广泛关注。值得注意的是，某些此类化合物与光诱导的激发自旋态俘获（LIESST）效应有关，后者负责其自旋态的光学转换。然而，与铁（II）配合物相反，显示出李斯特效应的铁（III）配合物的报道受到一定限制。这篇综述概述了显示LIESST效应的SCO铁（III）系统的实例。

更新日期：2020-12-17

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