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Grinding enhances the magnetic hardness of heterometallic diruthenium(II,III) carbonates with a kagome lattice structure
Dalton Transactions ( IF 3.5 ) Pub Date : 2020-11-16 , DOI: 10.1039/d0dt03807e Li-Na Feng 1, 2, 3, 4, 5 , Yu-Chen Tian 1, 2, 3, 4, 5 , Jing-Yu Li 1, 2, 3, 4, 5 , Jian-Hui Yang 1, 2, 3, 4, 5 , Bin Liu 1, 2, 3, 4, 5
Dalton Transactions ( IF 3.5 ) Pub Date : 2020-11-16 , DOI: 10.1039/d0dt03807e Li-Na Feng 1, 2, 3, 4, 5 , Yu-Chen Tian 1, 2, 3, 4, 5 , Jing-Yu Li 1, 2, 3, 4, 5 , Jian-Hui Yang 1, 2, 3, 4, 5 , Bin Liu 1, 2, 3, 4, 5
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The assembly of paddle–wheel Ru2 building units affords a new trimetallic carbonate, Cs3Cd(H2O)6[{Cd(H2O)3}2{Ru2(CO3)4}3]·10H2O (1), that contains structurally near-perfect kagome layers, {Ru2(CO3)4}n3n−, linked by octahedral Cd(H2O)32+ into a nanoscale kagome network exhibiting ferromagnetic ordering below 3.5 K. The investigation of influences of the grinding method on the crystal samples of compound 1 reveals that the coercivity increases from ∼2.5 Oe to 44.0 Oe upon a grinding treatment for 180 minutes. The results demonstrate that compound 1 can vary from a soft magnet to a hard magnet simply by manually grinding the crystal samples to the nanoscale.
中文翻译：
研磨可提高具有kagome晶格结构的杂金属碳酸二钌（II，III）的磁硬度
桨轮Ru 2建筑单元的组装提供了一种新的三金属碳酸盐Cs 3 Cd（H 2 O）6 [{Cd（H 2 O）3 } 2 {Ru 2（CO 3）4 } 3 ]·10H 2 O（1），其中包含结构上近乎完美戈薇层，{茹2（CO 3）4 } ñ 3 ñ - ，由八面体镉联（H 2 O）3 2+在低于3.5 K的铁电有序纳米级kagome网络中，研磨方法对化合物1晶体样品的影响研究表明，经过180分钟的研磨处理，矫顽力从约2.5 Oe增至44.0 Oe。结果表明，仅通过手动将晶体样品研磨至纳米级，化合物1即可从软磁铁变为硬磁铁。
更新日期：2020-11-27
中文翻译：
研磨可提高具有kagome晶格结构的杂金属碳酸二钌（II，III）的磁硬度
桨轮Ru 2建筑单元的组装提供了一种新的三金属碳酸盐Cs 3 Cd（H 2 O）6 [{Cd（H 2 O）3 } 2 {Ru 2（CO 3）4 } 3 ]·10H 2 O（1），其中包含结构上近乎完美戈薇层，{茹2（CO 3）4 } ñ 3 ñ - ，由八面体镉联（H 2 O）3 2+在低于3.5 K的铁电有序纳米级kagome网络中，研磨方法对化合物1晶体样品的影响研究表明，经过180分钟的研磨处理，矫顽力从约2.5 Oe增至44.0 Oe。结果表明，仅通过手动将晶体样品研磨至纳米级，化合物1即可从软磁铁变为硬磁铁。
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