Synthesis of Sustainable Polyesters via Organocatalytic Ring‐Opening Polymerization of O‐carboxyanhydrides: Advances and Perspectives,Macromolecular Rapid Communications

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Synthesis of Sustainable Polyesters via Organocatalytic Ring‐Opening Polymerization of O‐carboxyanhydrides: Advances and Perspectives
Macromolecular Rapid Communications ( IF 4.2 ) Pub Date : 2020-11-26 , DOI: 10.1002/marc.202000535
Jianqun Wang ₁ , Youhua Tao ₁

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Sustainable polyesters can be furnished via ring‐opening polymerization (ROP) of O‐carboxyanhydrides (OCAs). Various catalysts, especially metal‐based catalysts, are devised to achieve controlled ROP of OCAs. In the following mini review, the recent progress on the organocatalytic ROP of OCAs, including the usage of thiourea‐based bifunctional single‐molecule organocatalysts for eliminating epimerization in OCAs polymerization is summarized. Moreover, the future development of the organocatalytic ROP of OCAs for the synthesis of sustainable polyesters will be discussed.

中文翻译：

通过有机催化O-羧基酐的开环聚合合成可持续聚酯：进展和前景

可持续聚酯可以通过O-羧基酐（OCA）的开环聚合（ROP）提供。设计了各种催化剂，特别是金属基催化剂来实现OCA的受控ROP。在下面的微型综述中，总结了OCA的有机催化ROP的最新进展，包括使用基于硫脲的双功能单分子有机催化剂消除OCA聚合中的差向异构化。此外，将讨论用于合成可持续聚酯的OCA的有机催化ROP的未来发展。

更新日期：2020-11-26

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