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Iron-doped carbon electrode materials derived from polyethersulfone
Journal of Energy Storage ( IF 8.9 ) Pub Date : 2020-11-25 , DOI: 10.1016/j.est.2020.102099
Dichen Wu , Tianqi He , Abdalazeez Ismail Mohamed Albashir , Yongtao Tan , Fen Ran

In this work, carbon materials are prepared by sintering polyethersulfone membrane as precursor, and oxygen-containing functional groups are introduced into its surface with concentrated nitric acid as modifier. Then, the characteristics of oxygen-containing functional groups are used to adsorb iron ions to prepare iron-doped carbon material. And after doping with iron, the material not only has higher capacitance (227.9 F/g at 0.5 A/g), but also has better rate performance and cycling stability. Specifically, with the current densities increased from 0.5 A/g to 5 A/g, the retention rate of PES-C-Fe3 is 74.84 %, while that of the original carbon material is only 51.83 %. Moreover, the cycle life of the original carbon material decreases to 77.55 % after 1, 000 cycles, but PES-C-Fe3 can maintain 82.79 % of the initial capacitance after 10, 000 cycles.



中文翻译:

聚醚砜衍生的铁掺杂碳电极材料

在该工作中,通过烧结聚醚砜膜作为前体来制备碳材料,并用浓硝酸作为改性剂将含氧官能团引入其表面。然后,利用含氧官能团的特性吸附铁离子,从而制备掺杂铁的碳材料。在掺杂铁后,该材料不仅具有更高的电容(0.5 A / g时为227.9 F / g),而且还具有更高的倍率性能和循环稳定性。具体地,当电流密度从0.5A / g增加到5A / g时,PES-C-Fe3的保留率为74.84%,而原始碳材料的保留率为仅51.83%。此外,经过1000次循环后,原始碳材料的循环寿命降低至77.55%,但PES-C-Fe3在10次循环后仍可保持初始电容的82.79%,

更新日期:2020-11-26
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