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Synthesis of a Cobalt Coordination Polymer Based on 4-(1 H -Imidazol-1-yl)phenyl)methanone and Fumaric Acid
Crystallography Reports ( IF 0.6 ) Pub Date : 2020-11-25 , DOI: 10.1134/s1063774520070226
S-W. Sun , G.-F. Wang , J. Song , B.-W. Chang

Abstract

A cobalt coordination polymer with V-shaped ligands, {[Co0.5(L1) ⋅ (C4H2O4)0.5] ⋅ 0.25H2O}n, (L1 = 4-(1H-imidazol-1-yl)phenyl)methanone, C4H2O4 = fumarate) has been synthesized under the solvothermal conditions. It has been characterized by elemental analysis, FT-IR spectroscopy, and single-crystal X-ray diffraction analysis. The crystal is crystallized in the monoclinic space group C2/m with the unit cell parameters a = 10.6921(6) Å, b = 20.7735(10) Å, c = 8.8688(5) Å, and β = 107.615(6)°, Z = 4. X-ray crystal analysis reveals that the 1D [Co(L1)4] chains are linked by two adjacent fumarate ligands to form a 2D framework.



中文翻译:

基于4-(1 H-咪唑-1-基)苯基)甲酮和富马酸的钴配位聚合物的合成

摘要

具有V形配体{[Co 0.5L 1)⋅(C 4 H 2 O 40.5 ]⋅0.25H 2 O} n的钴配位聚合物,(L 1  = 4-(1 H -imidazol-1在溶剂热条件下合成了(C 1 H 2 O 4 =富马酸酯)。它的特征在于元素分析,FT-IR光谱和单晶X射线衍射分析。晶体在单斜空间群C 2 / m中结晶晶胞参数a = 10.6921(6)Å,b = 20.7735(10)Å,c = 8.8688(5)Å,β= 107.615(6)°,Z = 4.X射线晶体分析表明1D [Co(L 14 ]链由两个相邻的富马酸酯配体连接形成2D骨架。

更新日期:2020-11-25
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