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Chirality reversal, enhancement and transfer by pH-adjusted surfactant assembly
Chemical Communications ( IF 4.3 ) Pub Date : 2020-11-24 , DOI: 10.1039/d0cc07008d
Zhanglang Zhou 1, 2, 3, 4, 5 , Jin Zhou 6, 7, 8, 9, 10 , Lan Chen 6, 7, 8, 9, 10 , Qian Zhao 1, 2, 3, 4, 5 , Chun Zhang 1, 2, 3, 4, 5 , Guanglu Ge 6, 7, 8, 9, 10
Affiliation  

The controllable chirality reversal and enhancement at a supramolecular level is crucial for the synthesis and applications of circularly active materials, which has been achieved by a pH-adjusted amphiphilic chiral surfactant assembly approach, and reveals the relationship between the chirality behavior and its assembly morphology in a non-covalent interaction regime and its ability to transfer chirality from chiral molecules to achiral ones under appropriate conditions.

中文翻译:

通过pH调节的表面活性剂组装进行手性逆转,增强和转移

在超分子水平上可控的手性反转和增强对于合成和应用环状活性材料至关重要,这是通过pH调节的两亲性手性表面活性剂组装方法实现的,并揭示了手性行为与其组装形态之间的关系。非共价相互作用机制及其在适当条件下将手性从手性分子转移至非手性分子的能力。
更新日期:2020-11-25
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