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RbB3O4F2: a rubidium fluorooxoborate with an unprecedented [B3O5F2]3− functionalized unit and a large birefringence
Chemical Communications ( IF 4.3 ) Pub Date : 2020-11-11 , DOI: 10.1039/d0cc06851a Zixiu Lu 1, 2, 3, 4, 5 , Fangfang Zhang 1, 2, 3, 4, 5 , Abudukadi Tudi 1, 2, 3, 4, 5 , Zhihua Yang 1, 2, 3, 4, 5 , Shilie Pan 1, 2, 3, 4, 5
Chemical Communications ( IF 4.3 ) Pub Date : 2020-11-11 , DOI: 10.1039/d0cc06851a Zixiu Lu 1, 2, 3, 4, 5 , Fangfang Zhang 1, 2, 3, 4, 5 , Abudukadi Tudi 1, 2, 3, 4, 5 , Zhihua Yang 1, 2, 3, 4, 5 , Shilie Pan 1, 2, 3, 4, 5
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A new rubidium fluorooxoborate, RbB3O4F2, was structurally designed and synthesized by using the strategy of fluorine-introduction into borates. Interestingly, RbB3O4F2 presents the novel [B3O4F2]− chains formed by the unprecedented [B3O5F2]3− fundamental building block. More importantly, RbB3O4F2 has a large birefringence and a deep-UV cutoff edge. The finding of novel [B3O5F2]3− FBB and [B3O4F2]− chains in RbB3O4F2 greatly enriches the structural diversity of fluorooxoborates.
中文翻译：
RbB3O4F2：具有前所未有的[B3O5F2] 3-功能化单元和大双折射的氟氧硼酸rub
利用氟引入硼酸盐的策略，设计合成了一种新的氟代硼酸orRbB 3 O 4 F 2。有趣的是，RbB 3 O 4 F 2呈现了由前所未有的[B 3 O 5 F 2 ] 3-基本单元组成的新型[B 3 O 4 F 2 ] -链。更重要的是，RbB 3 O 4 F 2具有大的双折射和深紫外截止边缘。小说的发现[B 3 ORbB 3 O 4 F 2中的5 F 2 ] 3− FBB和[B 3 O 4 F 2 ] −链极大地丰富了氟硼酸盐的结构多样性。
更新日期：2020-11-25
中文翻译：
RbB3O4F2：具有前所未有的[B3O5F2] 3-功能化单元和大双折射的氟氧硼酸rub
利用氟引入硼酸盐的策略，设计合成了一种新的氟代硼酸orRbB 3 O 4 F 2。有趣的是，RbB 3 O 4 F 2呈现了由前所未有的[B 3 O 5 F 2 ] 3-基本单元组成的新型[B 3 O 4 F 2 ] -链。更重要的是，RbB 3 O 4 F 2具有大的双折射和深紫外截止边缘。小说的发现[B 3 ORbB 3 O 4 F 2中的5 F 2 ] 3− FBB和[B 3 O 4 F 2 ] −链极大地丰富了氟硼酸盐的结构多样性。
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