Recent advances in electroanalytical drug detection by porphyrin/phthalocyanine macrocycles: developments and future perspectives,Analyst

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Recent advances in electroanalytical drug detection by porphyrin/phthalocyanine macrocycles: developments and future perspectives
Analyst ( IF 3.6 ) Pub Date : 2020-11-10 , DOI: 10.1039/d0an01734e
Josué M. Gonçalves _{1,

2,

3,

4} , Bernardo A. Iglesias _{4,

5,

6,

7,

8} , Paulo R. Martins _{1,

4,

9,

10} , Lúcio Angnes _{1,

2,

3,

4}

Affiliation

Porphyrins and phthalocyanines are promising π-conjugated compounds with fantastic photochemical and electrochemical properties which are present in nature in more systems than we are generally aware. The electrochemical properties of these large aromatic molecules are also unique, endowing them with the ability to catalyze a wide range of redox reactions. The macrocycle core of these molecules is extremely favorable for the complexation of several metal ions, resulting in molecules with tunable properties. Porphyrins and phthalocyanines are able to form highly organized films, with high conductivity and great robustness and their use was explored to build a great number of electrochemical and photoelectrochemical sensors for many varied applications, one among them being drug analysis. This review will focus on the potential of the electrodes modified with attractive porphyrins and phthalocyanines for this application. The papers published in the last 3 years were closely evaluated.

中文翻译：

卟啉/酞菁大环化合物在电分析药物检测中的最新进展：发展和未来展望

卟啉和酞菁是有前途的π-共轭化合物，具有出色的光化学和电化学性能，这些性质存在于自然界中，比我们通常所知道的更多。这些大的芳族分子的电化学性质也是独特的，使它们具有催化多种氧化还原反应的能力。这些分子的大环核心对于几种金属离子的络合极为有利，从而使分子具有可调谐的特性。卟啉和酞菁能够形成高度有序的膜，具有高电导率和强大的鲁棒性，并且探索使用它们来构建许多用于多种应用的电化学和光电化学传感器，其中之一是药物分析。这篇综述将集中在用有吸引力的卟啉和酞菁修饰的电极对这种应用的潜力上。最近三年发表的论文受到了严格的评估。

更新日期：2020-11-25

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