Cover Feature: Structure‐Directing Roles of Organic Molecules in the Formation of Aluminosilicate and Aluminophosphate Molecular Sieves Revealed by 2D 1H DQ‐SQ NMR Spectroscopy (Chem. Eur. J. 6/2021),Chemistry - A European Journal

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Cover Feature: Structure‐Directing Roles of Organic Molecules in the Formation of Aluminosilicate and Aluminophosphate Molecular Sieves Revealed by 2D 1H DQ‐SQ NMR Spectroscopy (Chem. Eur. J. 6/2021)
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2020-11-24 , DOI: 10.1002/chem.202004209
Fangyan Liu ₁ , Biao Wang ₁ , Xiaolong Liu ₁

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Molecular sieves are generally prepared under hydrothermal conditions with reactions happening in “black box” autoclaves; the crystallization mechanism of molecular sieves is still a mystery, therefore, which is depicted by the UFO in the cover image. Further understanding of the crystallization mechanism of molecular sieves is driven by the broad range of usefulness and unique properties they possess. In this work, 2D 1H DQ‐SQ NMR results clearly demonstrate that it is not only the electrostatic interactions between organic structure‐directing agents (OSDAs) and the framework, but also the correlation among OSDAs playing the dominant structural directing roles during the crystallization process. More information can be found in the Communication by X. Liu et al. on page 1955.

中文翻译：

封面人物：通过2D 1H DQ-SQ NMR光谱揭示的有机分子在硅铝酸盐和铝磷酸盐分子筛形成中的结构指导作用（Chem。Eur。J. 6/2021）

分子筛通常在水热条件下制备，反应发生在“黑匣子”高压釜中。因此，分子筛的结晶机理仍然是一个谜，这由UFO在封面图像中描述。对分子筛结晶机理的进一步理解是由其广泛的实用性和独特性能决定的。在这项工作中，二维1H DQ-SQ NMR结果清楚地表明，这不仅是有机结构导向剂（OSDA）与骨架之间的静电相互作用，而且是OSDA之间的相关性，它们在结晶过程中起着主要的结构导向作用。有关更多信息，请参见X. Liu等人的来文。在1955页。

更新日期：2021-01-27

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