Synthetic Application of Cyclodextrins in Combination with Metal Ions, Complexes, and Metal Particles,ChemCatChem

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Synthetic Application of Cyclodextrins in Combination with Metal Ions, Complexes, and Metal Particles
ChemCatChem ( IF 3.8 ) Pub Date : 2020-11-24 , DOI: 10.1002/cctc.202001610
Árpád Molnár ₁

Affiliation

Cyclodextrins are green, environmentally benign products available through the enzymatic degradation of starch for a multitude of varied applications. This review attempts to collect useful information with respect to catalytic studies performed with the use of cyclodextrin and modified cyclodextrin preparations applied in combination of or loaded with varied catalytically active species including metal ions, complexes, and metal particles. Major sections are about their use in hydrogenation, reduction, oxidation, hydroformylation and coupling reactions. Additional sections include their utilization in ring formation and ring opening as well as degradation of pollutants. In the last part, examples about ester hydrolysis, hydroboration and hydrosilylation, as well as hydrogen production are treated. Data collected and analyzed indicate the importance and high potential of cyclodextrin‐based catalysts in sustainable chemistry.

中文翻译：

环糊精与金属离子，络合物和金属颗粒结合的合成应用

环糊精是绿色的，对环境无害的产品，可通过对淀粉进行酶促降解来进行多种应用。这篇综述试图收集有关使用环糊精和修饰的环糊精制剂进行催化研究的有用信息，这些制剂与多种催化活性物质（包括金属离子，络合物和金属颗粒）组合使用或负载了多种催化活性物质。主要部分是关于它们在氢化，还原，氧化，加氢甲酰化和偶联反应中的用途。其他部分包括它们在成环和开环以及污染物降解中的利用。在最后一部分中，讨论了有关酯水解，硼氢化和氢化硅烷化以及产氢的实例。

更新日期：2020-11-24

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