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Multicolor tunable emission and energy transfer in AlN:Tb 3+ ,Eu 3+ phosphors
Journal of Materials Science: Materials in Electronics ( IF 2.8 ) Pub Date : 2020-11-24 , DOI: 10.1007/s10854-020-04756-y
Zhipeng Fan , Yaqin Qie , Dengkui Guo , Yixuan Liu , Fanqi Kong , Zhan Shi , Hua Yang

Tb3+ and Eu3+ co-doped AlN phosphors are triumphantly synthesized by means of a simple solid-state route at 880 °C. The crystal structure, morphology, elements analysis and photoluminescence excitation and emission spectra are studied in detail. Tb3+ and Eu3+ co-doped AlN phosphors possess hexagonal structure and are composed of some irregular spherical particles. AlN:Tb3+ phosphors present intense emission under excitation wavelength at 338 nm, which is originating from 5D4 → 7FJ (J = 6, 5, 4, 3) transitions of Tb3+ ions. In addition, AlN:Tb3+,Eu3+ phosphors also display intense emission under excitation wavelength at 338 nm. The corresponding emission color of AlN:Tb3+,Eu3+ phosphors presents a trend of gradual change from green light to red light on account of energy transfer behavior from Tb3+ to Eu3+, which signifys that multicolor emitting AlN:Tb3+,zEu3+ phosphors can be applied in multicolor display.



中文翻译:

AlN:Tb 3+,Eu 3+荧光粉中的多色可调发射和能量转移

Tb 3+和Eu 3+共掺杂的AlN磷光体是通过简单的固态路线在880°C凯旋合成的。详细研究了晶体结构,形态,元素分析以及光致发光激发和发射光谱。Tb 3+和Eu 3+共掺杂的AlN荧光粉具有六边形结构,由一些不规则的球形颗粒组成。AlN:Tb 3+荧光粉在338 nm的激发波长下呈现强发射,这是 由于Tb 3+离子的5 D 4  →  7 F JJ = 6,5,4,3)跃迁引起的。另外,AlN:Tb3+,Eu 3+荧光粉在338 nm的激发波长下也显示出强发射。AlN:Tb 3+,Eu 3+荧光粉的相应发射颜色由于从Tb 3+到Eu 3+的能量转移行为而呈现出从绿光到红光逐渐变化的趋势,这表明发出多色的AlN:Tb 3+z Eu 3+荧光粉可应用于多色显示。

更新日期:2020-11-25
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