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Phonon properties and photo-thermal oxidation of micromechanically exfoliated antimonene nanosheets
2D Materials ( IF 4.5 ) Pub Date : 2020-11-21 , DOI: 10.1088/2053-1583/abb877
Michael Fickert 1 , Mhamed Assebban 1, 2 , Josep Canet-Ferrer 2 , Gonzalo Abelln 1, 2
Affiliation  

Two-dimensional (2D) sheets of antimonene have attracted increasing attention due to their unique physical and chemical properties prompting potential for diverse applications. We present a facile method to prepare high-quality antimonene nanosheets (ANSs) by micromechanical exfoliation on SiO2/Si substrate. The temperature- and laser power-dependent Raman studies of exfoliated ANSs are reported and analyzed. It was found that both the out-of-plane A1g and the in-plane Eg modes red-shift linearly with increase in temperature, pointing towards anharmonic vibrations of the lattice. The thermal response of the ANSs on a SiO2/Si surface is also described using numerical simulation of the heat transfer to study their laser-induced oxidation mechanisms. These results offer a deeper understanding of the phonon properties and oxidation susceptibility of 2D antimonene paving the way for the development of antimonene-based technologies, such as electronic devices or photothermal cancer therapy.



中文翻译:

微机械剥落的锑烯纳米片的声子性质和光热氧化

二维(2D)锑锭片因其独特的物理和化学性质而引起了越来越多的关注,这提示了其在各种应用中的潜力。我们提出了一种简便的方法,通过在SiO 2 / Si基底上进行微机械剥离来制备高质量的锑烯纳米片(ANSs)。剥落的ANS的温度和激光功率依赖性拉曼研究得到报道和分析。已经发现,平面外的A 1g和平面内的E g都随着温度的升高而线性地红移,这指向晶格的非谐振动。ANS 2在SiO 2上的热响应还使用传热的数值模拟来描述/ Si表面,以研究其激光诱导的氧化机理。这些结果使人们对2D锑的声子特性和氧化敏感性有了更深入的了解,为基于锑的技术(例如电子设备或光热癌症疗法)的发展铺平了道路。

更新日期:2020-11-21
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