Sixty Years of the van der Waals and Platteeuw Model for Clathrate Hydrates—A Critical Review from Its Statistical Thermodynamic Basis to Its Extensions and Applications,Chemical Reviews

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Sixty Years of the van der Waals and Platteeuw Model for Clathrate Hydrates—A Critical Review from Its Statistical Thermodynamic Basis to Its Extensions and Applications
Chemical Reviews ( IF 51.4 ) Pub Date : 2020-11-23 , DOI: 10.1021/acs.chemrev.0c00494
Fernando de Azevedo Medeiros _{1,

2} , Iuri Soter Viana Segtovich ₂ , Frederico Wanderley Tavares _{2,

3} , Amadeu K. Sum ₄

Affiliation

In light of the 60-year anniversary of the publishing of “Clathrate Solutions” by van der Waals and Platteeuw in 2019, we present a critical review of the famed solid solution model first disclosed in 1959. First, we lay out the groundwork in the 1950s aimed at the development of a phenomenological approach to clathrate modeling. Then we review the statistical thermodynamics fundamentals of the model, considering van der Waals and Platteeuw’s earlier works, to obtain a consistent interpretation of the model. We turn our focus to clathrate hydrates and discuss the major contributions that led to the current state-of-the-art of gas hydrate thermodynamic modeling. Finally, we present some of the areas in clathrate thermodynamics that we foresee as the new frontiers in this subject. We expect this review to help newcomers to clathrate science in elucidating some subtle aspects of the model and to intrigue clathrate experts with a fresh look on this well-established solid solution model.

中文翻译：

包合物水合物的范德瓦尔斯和普拉特euw模型六十年—从其统计热力学基础到其扩展和应用的批判性评论

鉴于van der Waals和Platteeuw于2019年发布“氯酸盐溶液” 60周年，我们对1959年首次公开的著名固体溶液模型进行了批判性回顾。首先，我们在1950年代旨在开发一种用于包合物建模的现象学方法。然后，考虑范德华斯和普拉特乌夫的早期工作，我们回顾了模型的统计热力学基础知识，从而获得了对该模型的一致解释。我们将重点放在笼统的水合物上，并讨论导致当前最新的天然气水合物热力学建模的主要贡献。最后，我们介绍了包合物热力学中的一些领域，我们认为它们是该领域的新前沿。

更新日期：2020-12-23

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