Phosphorus Ligands from the Zhang Lab: Design, Asymmetric Hydrogenation, and Industrial Applications,Chinese Journal of Chemistry

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Phosphorus Ligands from the Zhang Lab: Design, Asymmetric Hydrogenation, and Industrial Applications
Chinese Journal of Chemistry ( IF 5.5 ) Pub Date : 2020-11-23 , DOI: 10.1002/cjoc.202000605
Feng Wan ₁ , Wenjun Tang _{1,

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Affiliation

Chiral phosphorus ligands have played a crucial role for the recent advances in asymmetric catalysis. This review summarizes chiral phosphorus ligands developed from the Laboratory of Professor Xumu Zhang in the latest 25 years. A number of iconic phosphorus ligands including bisphosphorus ligands with rigid chiral backbone such as BICP, PennPhos, TunePhos, and f‐Binaphane, P‐chiral bisphosphorus ligands TangPhos, Binapine, and DuanPhos, phosphine‐phosphoramidte ligand YanPhos, noncovalent interaction‐assisted ferrocenyl phosphorus ligand ZhaoPhos and WudaPhos, and tridentate ferrocenyl phosphorus ligands f‐amphox are introduced, and their applications in asymmetric hydrogenation are emphasized.

中文翻译：

张实验室的磷配体：设计，不对称氢化和工业应用

手性磷配体对于不对称催化的最新进展起着至关重要的作用。这篇综述总结了张旭牧教授实验室在最近25年中开发的手性磷配体。许多标志性的磷配体包括具有刚性手性骨架的双磷配体，例如BICP，PennPhos，TunePhos和f- Binaphane，P-手性双磷配体TangPhos，Binapine和DuanPhos，膦-磷酰胺配体YanPhos，非共价相互作用辅助的二茂铁磷引入了ZhaoPhos和WudaPhos配体，以及三齿二茂铁磷配体f- amphox，并强调了它们在不对称氢化中的应用。

更新日期：2020-11-23

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