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Bioethanol steam reforming over monoliths washcoated with RhPt/CeO2–SiO2: The use of residual biomass to stably produce syngas
International Journal of Hydrogen Energy ( IF 8.1 ) Pub Date : 2020-11-23 , DOI: 10.1016/j.ijhydene.2020.10.271
Bernay Cifuentes , July Gómez , Néstor Sánchez , Laura Proaño , Felipe Bustamante , Martha Cobo

Ethanol steam reforming of synthetic bioethanol (i.e., anhydrous ethanol plus water), as well as bioethanol obtained from glucose standards and sugarcane press-mud was evaluated on monoliths washcoated with RhPt/CeO2–SiO2. Tests with synthetic bioethanol indicated that the lower pressure drop favors higher ethanol conversion in the monoliths with respect to the powder samples. Also, two monoliths in series with 0.08 gcat/cm3 improved H2 yield compared to just one monolith with 0.16 gcat/cm3. Similarly, a decrease in the amount of carrier gas contributes to diffusion limitations in the monoliths, reducing the H2/CO ratio. Monoliths stability was also evaluated with “real” bioethanol samples (from glucose standards and sugarcane press-mud-SPM). In all cases, a syngas with >60% of H2 was produced. For SPM-bioethanol, 3.1 ± 0.2 mol H2/mol EtOH were obtained without evidence of deactivation for 120 h, at a cost of 6.9 $/kgH2, becoming a promising way to develop a technology for sustainable energy production.



中文翻译:

用RhPt / CeO 2 -SiO 2修补的整料上的生物乙醇蒸汽重整:利用残余生物质稳定生产合成气

在用RhPt / CeO 2 -SiO 2修补的整料上评估了合成生物乙醇(即无水乙醇加水)的乙醇蒸汽重整,以及从葡萄糖标准品和甘蔗压泥获得的生物乙醇。合成生物乙醇的测试表明,相对于粉末样品,较低的压降有利于整体料中较高的乙醇转化率。而且,与仅一个具有0.16g cat / cm 3的整体物相比,两个具有0.08g cat / cm 3的整体物提高了H 2产率。同样,载气量的减少也有助于整体材料中的扩散限制,从而降低了H 2/ CO比。还使用“真实的”生物乙醇样品(来自葡萄糖标准品和甘蔗压泥-SPM)评估了整料的稳定性。在所有情况下,用H> 60%合成气2被制造。对于SPM-生物乙醇,在没有证据表明失活120小时的情况下,获得了3.1±0.2 mol H 2 / mol EtOH,成本为6.9 $ / kgH 2,成为开发可持续能源生产技术的一种有前途的方法。

更新日期:2021-01-07
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