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INVESTIGATION OF TNT RED WASTEWATER TREATMENT TECHNOLOGY USING THE COMBINATION OF ADVANCED OXIDATION PROCESSES
Science of the Total Environment ( IF 8.2 ) Pub Date : 2020-11-21 , DOI: 10.1016/j.scitotenv.2020.143852
Dinh Nhi Bui , Thi Thao Minh

Different types of advanced oxidation processes and their combinations such as O3/H2O2/UV, O3/Fenton/UV, O3/TiO2/UV, Fenton/H2O2/UV, Fenton/TiO2/UV, TiO2/H2O2/UV, TiO2/H2O2/O3/UV, TiO2/O3/Fenton/UV, TiO2/H2O2/Fenton/UV and O3/H2O2/Fenton/UV were studied for the treatment of undiluted red wastewater from Z113 Factory. The treatment efficiency was evaluated by analyzing chemical oxygen demand (COD) reduction, % degradation of α-TNT, 2,4-DNT, 2,6-DNT, 2,4-DNT-3-SO3Na and 2,4-DNT-5-SO3Na. Among studied processes Fenton/TiO2/O3/UV was the most effective technology to treat red wastewater. It allows to reduce > 99% of COD, α-TNT, 2,4-DNT, 2,6-DNT, 2,4-DNT-3-SO3Na and 2,4-DNT-5-SO3Na after 30h of treatment with optimum operating conditions: rotation speed of 600 rpm, pH of 4 and temperature of 40oC. According to the chromatograms obtained by gas chromatograph/mass spectrometer (GC/MS), intermediates of the decomposition of pollutants in red wastewater were identified. GC/MS, HPLC, UV-vis and Bacterial Toxicity test were used to assess effluent quality changes before and after treatment. By economic analysis, the studied process had the potential to apply in practice to treat real wastewater at the Z113 Factory.



中文翻译:

结合高级氧化工艺对TNT红色废水的处理技术研究

不同类型的高级氧化工艺及其组合,例如O 3 / H 2 O 2 / UV,O 3 / Fenton / UV,O 3 / TiO 2 / UV,Fenton / H 2 O 2 / UV,Fenton / TiO 2 / UV,TiO 2 / H 2 O 2 / UV,TiO 2 / H 2 O 2 / O 3 / UV,TiO 2 / O 3 / Fenton / UV,TiO 2 / H 2 O 2 / Fenton / UV和O 3 / H 2 O 2/ Fenton / UV被用于Z113工厂的未稀释红色废水的处理。通过分析化学需氧量(COD)的减少,α-TNT,2,4-DNT,2,6-DNT,2,4-DNT-3-SO 3 Na和2,4-的降解百分比来评估处理效率DNT-5-SO 3 Na。在研究的方法中,Fenton / TiO 2 / O 3 / UV是处理红色废水的最有效技术。它可以减少> 99%的COD,α-TNT,2,4-DNT,2,6-DNT,2,4-DNT-3-SO 3 Na和2,4-DNT-5-SO 3 Na在最佳操作条件下处理30小时:转速为600 rpm,pH为4,温度为40 oC.根据气相色谱/质谱仪(GC / MS)获得的色谱图,确定了红色废水中污染物分解的中间体。GC / MS,HPLC,UV-vis和细菌毒性测试用于评估处理前后废水的质量变化。通过经济分析,所研究的过程具有在Z113工厂中实际处理实际废水的潜力。

更新日期:2020-11-22
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