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Fabrication of BSCF-based mixed oxide ionic-electronic conducting multi-layered membrane by sequential electrophoretic deposition process
Journal of the European Ceramic Society ( IF 5.8 ) Pub Date : 2020-11-21 , DOI: 10.1016/j.jeurceramsoc.2020.11.024
Kento Ishii , Chika Matsunaga , Kiyoshi Kobayashi , Adam J. Stevenson , Caroline Tardivat , Tetsuo Uchikoshi

The Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF)-based multi-layered oxygen separation membrane was fabricated by the sequential electrophoretic deposition (EPD) process. A thin porous/dense bi-layer of BSCF was formed on a thick porous support of BSCF. The porous support prepared by a sacrificial template method using BSCF powder mixed with wheat starch (30 wt%) as a pore-forming agent, followed by uniaxial pressing and low-temperature sintering, was directly used as an EPD electrode. A thin BSCF layer was first formed on the porous support, and then a thin BSCF + PMMA (polymethyl methacrylate) layer was sequentially formed on the thin BSCF layer using a bimodal suspension of BSCF and PMMA. A 30-μm thin porous/dense bi-layer of BSCF of which the total thickness was obtained by optimizing the processes of EPD and subsequent co-sintering. The oxygen separation performance of 3.7 ml (STP) min−1 cm−2 at 860 °C was achieved for the BSCF-based multi-layered oxygen separation membrane.



中文翻译:

顺序电泳沉积法制备基于BSCF的复合氧化物离子导电多层膜

Ba 0.5 Sr 0.5 Co 0.8 Fe 0.2 O3 (BSCF)为基础的多层氧分离膜是通过顺序电泳沉积(EPD)工艺制备的。在BSCF的厚多孔载体上形成BSCF的薄多孔/致密双层。通过牺牲模板法使用BSCF粉末与小麦淀粉(30 wt%)混合作为成孔剂,然后单轴压制和低温烧结制备的多孔载体直接用作EPD电极。首先在多孔载体上形成薄的BSCF层,然后使用BSCF和PMMA的双峰悬浮液在薄的BSCF层上依次形成薄的BSCF + PMMA(聚甲基丙烯酸甲酯)层。30微米的BSCF多孔/致密双层,通过优化EPD和随后的共烧结工艺获得了总厚度。氧分离性能为3。-1厘米-2在860℃下对于基于BSCF-多层氧分离膜来实现。

更新日期:2021-01-22
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