The synthesis of green methanol from CO₂ and renewable H₂ is a key process for energy and chemistry transition, for which MOFs (metal-organic framework) type catalysts represent a novel class of thermo catalysts to address the quest of novel catalysts for low-temperature delocalized applications. This critical concise review analyses the state-of-the-art of MOFs catalysts for this reaction after introducing aspects related to their preparation, key features, and advantages as catalytic materials. The SWOT (strengths, weaknesses, opportunities and threats) analysis of their behavior from chemical reaction engineering and application perspectives remarks the need of turn the approach on their developments, besides addressing some current weaknesses such as stability in the reaction conditions and scalability of the synthesis procedure. New opportunities are evidenced in moving from CO₂ to methanol to CO₂ direct conversion to C²⁺ products, from olefins/aromatics to higher alcohols, which require a novel design of these catalytic materials.

由CO ₂和可再生H ₂合成绿色甲醇催化裂化是能源和化学转变的关键过程，MOF（金属-有机骨架）类型的催化剂代表了新型的热催化剂，以解决针对低温离域应用的新型催化剂的需求。这篇简明扼要的综述在介绍了与MOF催化剂制备有关的方面，关键特性以及作为催化材料的优势之后，分析了该反应的最新技术。从化学反应工程和应用的角度对其行为进行SWOT分析（优势，劣势，机会和威胁），除了解决一些当前的劣势（例如反应条件的稳定性和合成的可扩展性）外，还需要改变其发展方向。程序。从CO转移的新机会被证明₂从甲醇/ CO ₂直接转化为C ²⁺产物，从烯烃/芳烃到高级醇，这需要对这些催化材料进行新颖的设计。