A polyoxometalate-encapsulated nanocage cluster organic framework built from {Cu4P2} units and its efficient bifunctional electrochemical performance,Chemical Communications

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A polyoxometalate-encapsulated nanocage cluster organic framework built from {Cu4P2} units and its efficient bifunctional electrochemical performance
Chemical Communications ( IF 4.3 ) Pub Date : 2020-11-09 , DOI: 10.1039/d0cc06665f
Shaobin Li _{1,

2,

3,

4,

5} , Xiaoguo Tan _{1,

2,

3,

4,

5} , Ming Yue _{5,

6,

7,

8} , Li Zhang _{1,

2,

3,

4,

5} , Dongfeng Chai _{3,

5,

9,

10} , Wendi Wang _{1,

2,

3,

4,

5} , Hong Pan _{1,

2,

3,

4,

5} , Linlin Fan _{1,

2,

3,

4,

5} , Chunyan Zhao _{3,

5,

9,

10}

Affiliation

The first polyoxometalate (POM)-encapsulated twenty-four-nucleus organophosphorus-copper nanocage cluster organic framework has been constructed. Here, the phosphomolybdate POMs were incorporated into an octahedral nanocage cluster organic framework, and the resulting material exhibited highly efficient bifunctional electrochemical performance. The crystalline material showed a high specific capacitance of 366.3 F g⁻¹ at a current density of 3 A g⁻¹.

中文翻译：

由{Cu4P2}单元构建的多金属氧酸盐包裹的纳米笼簇有机骨架及其高效的双功能电化学性能

构造了第一个多金属氧酸盐（POM）封装的二十四核有机磷-铜纳米笼簇有机骨架。在此，将磷钼酸盐POMs掺入八面体纳米笼簇有机骨架中，所得材料表现出高效的双功能电化学性能。该晶体材料在3 A g ^-1的电流密度下显示出366.3 F g ^-1的高比电容。

更新日期：2020-11-21

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