Mono(hydrosilylation) of N-Heterocycles Catalyzed by B(C6F5)3 and Silylium Ion,Organometallics

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Mono(hydrosilylation) of N-Heterocycles Catalyzed by B(C6F5)3 and Silylium Ion
Organometallics ( IF 2.5 ) Pub Date : 2020-11-19 , DOI: 10.1021/acs.organomet.0c00697
William D. Petrushko ₁ , Georgii I. Nikonov ₁

Affiliation

Catalytic hydrosilylations of various N-heterocycles mediated by silylium ion and electrophilic borane catalysts are reported. The reactions proceed via intermediate silylquinolinium ions that give rise to a variety of reduced and coupling products. Generally, highly selective 1,4-regioselectivity is observed.

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