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Designing nickelate superconductors withd8configuration exploiting mixed-anion strategy
Physical Review Research ( IF 3.5 ) Pub Date : 2020-11-20 , DOI: 10.1103/physrevresearch.2.042032
Naoya Kitamine , Masayuki Ochi , Kazuhiko Kuroki

Inspired by a recently proposed superconducting mechanism for a new cuprate superconductor Ba2CuO3+δ, we theoretically design an unconventional nickelate superconductor with a d8 electron configuration. Our strategy is to enlarge the on-site energy difference between 3dx2y2 and other 3d orbitals by adopting halogens or hydrogen as out-of-plane anions, so that the 3d bands other than dxy2 lie just below the Fermi level for the d8 configuration, acting as incipient bands that enhance superconductivity. We also discuss a possible relevance of the present proposal to the recently discovered superconductor (Nd,Sr)NiO2.

中文翻译:

利用混合阴离子策略设计具有8位构型的镍酸超导体

受到最近提出的用于新型铜酸盐超导体的超导机制的启发 2氧化铜3+δ,我们从理论上设计了一种非常规的含镍超导体 d8电子配置。我们的策略是扩大现场之间的能量差3dX2-ÿ2 和别的 3d 通过采用卤素或氢作为平面外阴离子进入轨道 3d 乐队以外的乐队 dX-ÿ2 在费米水平之下 d8构型,充当增强超导性的初始带。我们还将讨论本建议与最近发现的超导体的可能关联性r氧化镍2
更新日期:2020-11-21
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