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Corymbia citriodora: A Valuable Resource from Australian Flora for the Production of Fragrances, Repellents, and Bioactive Compounds
ChemBioEng Reviews ( IF 6.2 ) Pub Date : 2020-11-20 , DOI: 10.1002/cben.202000013
Tyler Goodine 1 , Michael Oelgemöller 1, 2
Affiliation  

As global chemical manufacturing has historically relied on inexpensive feedstocks from the petrochemical industry, the identification of new naturally derived feedstocks represents an important and sustainable alternative. This review introduces Corymbia citriodora (Hook.) K.D.Hill & L.A.S.Johnson as an attractive renewable resource of natural compounds for organic chemical transformations. Although native to Australia, this plant species is now grown and harvested worldwide. The chemical composition of citriodora oils varies with location, harvesting season and age of leaves. Beyond their historic uses as fragrances or repellents, the more abundant terpenes found in citriodora oils such as citronellal, citronellol, and isopulegol have notable roles in the manufacture of fine chemicals. This review highlights several industrial processes intimately related to the citriodora terpenes, some advances in fragrances and repellents, as well as the use of these terpenes in the most recently reported synthesis of bioactive compounds. Where relevant, processes highlighting the adoption of green chemistry principles are presented and briefly discussed.

中文翻译:

桔梗Corymbia citriodora:来自澳大利亚植物群的宝贵资源,用于生产香料,驱虫剂和生物活性化合物

历史上,由于全球化学制造业一直依赖石油化工行业的廉价原料,因此,鉴定新的天然来源原料是一种重要且可持续的选择。这篇评论介绍了Corymbia citriodora(Hook。) KDHill和LASJohnson,这是一种用于有机化学转化的有吸引力的天然化合物可再生资源。尽管这种植物原产于澳大利亚,但现在已经在世界范围内种植和收获。柠檬柠檬油的化学成分随位置,收获季节和叶片年龄而变化。除了作为香精或驱虫剂的历史用途之外,柠檬酸中发现的更丰富的萜烯香茅醛,香茅醇和异胡薄荷醇等油在精细化学品的生产中具有显著作用。这篇综述着重介绍了与柠檬草萜烯有密切关系的几种工业过程,香料和驱虫剂的一些进展以及这些萜烯在最近报道的生物活性化合物合成中的用途。在适当的地方,介绍并简要讨论了强调采用绿色化学原理的过程。
更新日期:2020-12-16
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