Glasses with molar composition of 0.95[50B₂O₃-30BaO-(20-x)ZnO-xBi₂O₃]+0.05V₂O₅, x = 0, 5, 10, 15, and 20, are prepared. When the Bi₂O₃/ZnO ratio increases, some [BO4] units transform to the [BO3] units with the increase of non-bridging oxygens. The borate network is depolymerized and weakened, which may account for the decrease of the glass transition temperature. Aluminum pastes containing the glasses show good adhesion between Al powders and the SiN_x/Al₂O₃ passivation layer after firing. The SiN_x layer is only slightly deteriorated. Bi crystallites are observed from the glass matrix by the interfacial reaction.

制备具有摩尔比为0.95 [50B ₂ O ₃ -30BaO-（20- x）ZnO- x Bi ₂ O ₃ ] + 0.05V ₂ O _5的玻璃，x  ＝0、5、10、15和20。当Bi ₂ O ₃ / ZnO比值增加时，一些[BO4]单元会随着非桥连氧的增加而转变为[BO3]单元。硼酸盐网络解聚并减弱，这可能导致玻璃化转变温度降低。包含玻璃的铝浆在Al粉和SiN _x / Al ₂ O ₃之间显示出良好的附着力烧成后的钝化层。SiN _x层仅稍微劣化。通过界面反应从玻璃基质中观察到双微晶。