Two-dimensional black phosphorus (2D BP) and its derivatives has recently attracted significant research attention on energy storage devices due to its extremely high electronic conductivity, anisotropic structural advantages and high specific capacity. Through in-depth research, the performance defects of BP-based devices are discovered, which is mainly due to the poor chemical stability of BP. In order to solve the above issues, by integrating the unique properties of foreign materials and the advantages of BP into a single hybrid hetero-structure, a variety of black phosphorus derivatives (BPDs) have been constructed as emerging types of multifunctional materials. With the rapid development of BPDs, a timely review on this topic is in demand to further extend the application of BPDs in alkali metal-ion battery (AMIBs), especially sodium-ion batteries (SIBs) and potassium-ion batteries (PIBs), they are the new generation metal-ion batteries due to the abundance natural reserve and cost-effective merits of Na and K. Here, the design of BPDs with excellent stability/ion-kinetics and the progress of BPDs anodes for AMIBs are systematical reviewed, which are not only crucial for in-depth understanding of electrochemical energy storage mechanism but also to provide further insights and enabling rational design methodologies. Finally, the challenges of BPDs in the development of AMIBs are presented, hoping to provide some inspirations for the design and fabrication of advanced alkali metal energy storage systems.

二维黑磷（2D BP）及其衍生物由于其极高的电子电导率，各向异性的结构优势和高的比容量，最近在储能设备上引起了广泛的研究关注。通过深入的研究，发现了基于BP的设备的性能缺陷，这主要是由于BP的化学稳定性差所致。为了解决上述问题，通过将异物的独特性能和BP的优点整合到一个杂化异质结构中，已将多种黑磷衍生物（BPD）构造为新兴的多功能材料。随着BPD的飞速发展，需要对此主题进行及时的审查，以进一步扩展BPD在碱金属离子电池（AMIB）中的应用，尤其是钠离子电池（SIBs）和钾离子电池（PIBs），由于Na和K的丰富自然储备和具有成本效益的优点，它们是新一代的金属离子电池。系统评价了AMIB的稳定性/离子动力学和BPD阳极的进展，这不仅对深入了解电化学储能机理至关重要，而且对提供进一步的见解和合理的设计方法学也至关重要。最后，介绍了BPD在AMIB开发中所面临的挑战，希望为高级碱金属储能系统的设计和制造提供一些启发。由于Na和K的丰富自然储备以及具有成本效益的优点，它们是新一代的金属离子电池。在此，系统地回顾了具有优异稳定性/离子动力学的BPD的设计以及AMIB的BPD阳极的进展，这不仅对深入了解电化学储能机理至关重要，而且对于提供进一步的见解和实现合理的设计方法至关重要。最后，介绍了BPD在AMIB开发中所面临的挑战，希望为高级碱金属储能系统的设计和制造提供一些启发。由于Na和K的丰富自然储备以及具有成本效益的优点，它们是新一代的金属离子电池。在此，系统地回顾了具有优异稳定性/离子动力学的BPD的设计以及AMIB的BPD阳极的进展，这不仅对深入了解电化学储能机理至关重要，而且对于提供进一步的见解和实现合理的设计方法至关重要。最后，介绍了BPD在AMIB开发中所面临的挑战，希望为高级碱金属储能系统的设计和制造提供一些启发。这不仅对深入了解电化学储能机理至关重要，而且对于提供进一步的见解和实现合理的设计方法至关重要。最后，介绍了BPD在AMIB开发中所面临的挑战，希望为高级碱金属储能系统的设计和制造提供一些启发。这不仅对深入了解电化学储能机理至关重要，而且对于提供进一步的见解和实现合理的设计方法至关重要。最后，介绍了BPD在AMIB开发中所面临的挑战，希望为高级碱金属储能系统的设计和制造提供一些启发。