Electrochemical Oxidative C–H Thiocyanation or Selenocyanation of Imidazopyridines and Arenes,Synlett

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Electrochemical Oxidative C–H Thiocyanation or Selenocyanation of Imidazopyridines and Arenes
Synlett ( IF 1.7 ) Pub Date : 2020-11-17 , DOI: 10.1055/s-1299-3009
Ping Liu _{1,

2} , Peipei Sun ₁ , Ting Cui ₁ , Xiaofeng Zhang ₁ , Jun Lin _{1,

2} , Zitong Zhu ₁

Affiliation

Regioselective electrochemical oxidative C–H thiocyanation or selenocyanation of imidazopyridines was achieved by using an undivided electrolytic cell. Transition-metal- and oxidant-free conditions are striking features of this protocol. A library of thiocyanated imidazopyridines with a broad range of functional groups were synthesized in high yields. This method was also applicable to the thiocyanation or selenocyanation of some electron-rich arenes.

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