With the drastic increase of global energy and sensing demand in this century, the development of sustainable energy and highly sensitive sensor has become progressively paramount. Electrochemical energy storage devices with the ability to store sustainable energy, electrochemical-sensing and electrocatalysis technologies such as O₂ reduction reaction (ORR), O₂ evolution reaction (OER), H₂ evolution reaction (HER), CO₂ reduction reaction (CRR), and N₂ reduction reaction (NRR) are highly desired. The performances of these devices tightly rely on the electrode materials, which has aroused extensive attention on the exploitations of novel electrode active substances. Due to the outstanding structural designability, large specific surface area and adjustable active sites, electrically conductive metal-organic frameworks with redox-activity (ECMOFs) are regarded as the capable candidates of active substances for those electrochemical applications. This review introduces the conductive mechanisms of ECMOFs, provides the design strategies of ECMOFs electrodes and summarizes the recent advances on ECMOFs in electrochemical sensing, electrochemical energy storage and electrocatalysts in detail. Finally, the challenges and outlook of ECMOFs in the practical applications are systematically emphasized, which will open an avenue to the development of ECMOFs-based electrochemical devices.

随着本世纪全球能源和传感需求的急剧增长，可持续能源和高度灵敏的传感器的发展已变得至关重要。具有存储可持续能量的能力的电化学储能装置，电化学传感和电催化技术，例如O ₂还原反应（ORR），O ₂析出反应（OER），H ₂析出反应（HER），CO ₂还原反应（CRR） ）和N ₂还原反应（NRR）是非常需要的。这些装置的性能紧密依赖于电极材料，这引起了对新型电极活性物质的开发的广泛关注。由于出色的结构设计性，大的比表面积和可调节的活性位点，具有氧化还原活性的导电金属有机骨架（ECMOF）被认为是这些电化学应用中活性物质的有力候选者。这篇综述介绍了ECMOFs的导电机理，提供了ECMOFs电极的设计策略，并详细总结了ECMOFs在电化学传感，电化学储能和电催化剂方面的最新进展。最后，系统地强调了ECMOF在实际应用中的挑战和前景，