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Ultra-stable Eu3+-doped CsPbCl2Br1 perovskite quantum dots glass for optical temperature sensing
Journal of Rare Earths ( IF 4.9 ) Pub Date : 2020-11-18 , DOI: 10.1016/j.jre.2020.11.010
Yanxia Yu , Guangzhan Shao , Ling Ding , Huiling Zhang , Xiaojuan Liang , Weidong Xiang , Jianping Liu

In this work, Eu3+-doped CsPbCl2Br1 in borosilicate glass was successfully synthesized by the melt quenching annealing technique and crystallization method. This work reports a novel Eu3+-doped CsPbCl2Br1 perovskite quantum dots (QDs) glass with high sensitivity for optical temperature sensing. The relation of fluorescence intensity ratio (FIR) with the temperature was studied in the temperature range of 80–440 K. Notably, the maximum absolute temperature sensitivity (Sa) and relative temperature sensitivity (Sr) of Eu3+-doped CsPbCl2Br1 perovskite QDs glass can reach as high as 0.0315 K–1 and 3.097%/K, respectively. Meanwhile, Eu3+-doped CsPbCl2Br1 QDs glass demonstrates good water resistance, excellent thermal and cold cycling stability performance. The Eu3+-doped QDs glass materials can bring inspiration to the future exploration of rare earth ion-doped QDs glass material on the application of optical temperature sensing in the future.



中文翻译:

用于光学温度传感的超稳定 Eu3+ 掺杂 CsPbCl2Br1 钙钛矿量子点玻璃

本工作采用熔体淬火退火技术和结晶法成功合成了硼硅玻璃中掺Eu 3+ 的CsPbCl 2 Br 1。这项工作报告了一种新型的 Eu 3+掺杂的 CsPbCl 2 Br 1钙钛矿量子点 (QDs) 玻璃,它对光学温度传感具有高灵敏度。在80-440 K的温度范围内研究了荧光强度比(FIR)与温度的关系。值得注意的是,Eu 3+掺杂的CsPbCl的最大绝对温度灵敏度(S a)和相对温度灵敏度(S r21钙钛矿 QDs 玻璃可以分别达到 0.0315 K –1和 3.097%/K。同时,Eu 3+掺杂的CsPbCl 2 Br 1 QDs玻璃表现出良好的耐水性、优异的热循环和冷循环稳定性能。Eu 3+掺杂量子点玻璃材料可以为未来稀土离子掺杂量子点玻璃材料在光学温度传感应用方面的探索带来启示。

更新日期:2020-11-18
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